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s-Block Metal Complexes

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ISBN: 9783038425892 9783038425908 Year: Pages: VIII, 146 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemistry (General)
Added to DOAB on : 2017-12-06 12:48:40
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Abstract

The coordination chemistry of the s-block metals spans diverse fields, ranging from shielded coordination compounds over hydride to organometallic complexes for diverse applications. New developments pertain, not only to the lithium and magnesium chemistry with inspiring examples, such as heterobimetallic or heteroleptic complexes with special reactivity patterns, but the heavy s-block metals have progressively gained attention in various fields. Subvalent magnesium(I) derivatives are increasingly being used for reduction reactions, turbo-Grignard reagents show enhanced reactivity and tolerance toward functional groups, hydrides act as hydrogen storage materials, heavy Grignard reagents are available by straight forward procedures—just to name a few examples. Quantum chemical calculations deal with unique bonding situations and the relevance of d-orbital participation has been discussed to understand structure-reactivity relationships. Especially the complexes of the heavy alkaline earth metals are catalytically active in diverse reactions, promoting hydrofunctionalization reactions and Lewis acid catalysis. This Special Issue aims to highlight the structural and chemical diversity of s-block metal complexes, as well as the broad field of applications.

Organisation im soziotechnischen Gemenge

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Book Series: Edition Medienwissenschaft ISBN: 9783839437841 9783837637847 Year: Pages: 210 DOI: 10.14361/9783839437841 Language: German
Publisher: transcript Verlag Grant: Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
Subject: Sociology
Added to DOAB on : 2017-03-03 11:01:50
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Abstract

How do media and technologies structure our daily working lives? An organisational-sociological study.

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