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Pd-based Membranes. Overview and Perspectives

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ISBN: 9783038977025 Year: Pages: 190 DOI: 10.3390/books978-3-03897-703-2 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemical Engineering --- Technology (General)
Added to DOAB on : 2019-04-05 10:34:31
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Palladium (Pd)-based membranes have received a great deal of attention from both academia and industry thanks to their ability to selectively separate hydrogen from gas streams. The integration of such membranes with appropriate catalysts in membrane reactors allows for hydrogen production with CO2 capture that can be applied in smaller bioenergy or combined heat and power (CHP) plants, as well as in large-scale power plants. Pd-based membranes are therefore regarded as a Key Enabling Technology (KET) to facilitate the transition towards a knowledge-based, low-carbon, and resource-efficient economy. This Special Issue of the journal Membranes on “Pd-based Membranes: Overview and Perspectives” contains nine peer-reviewed articles. Topics include manufacturing techniques, understanding of material phenomena, module and reactor design, novel applications, and demonstration efforts and industrial exploitation.

Membrane and Membrane Reactors Operations in Chemical Engineering

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ISBN: 9783039210220 / 9783039210237 Year: Pages: 154 DOI: 10.3390/books978-3-03921-023-7 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering --- Environmental Engineering
Added to DOAB on : 2019-06-26 10:09:00
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This Special Issue is aimed at highlighting the potentialities of membrane and membrane reactor operations in various sectors of chemical engineering, based on application of the process intensification strategy. In all of the contributions, the principles of process intensification were pursued during the adoption of membrane technology, demonstrating how it may lead to the development of redesigned processes that are more compact and efficient while also being more environmental friendly, energy saving, and amenable to integration with other green processes. This Special Issue comprises a number of experimental and theoretical studies dealing with the application of membrane and membrane reactor technology in various scientific fields of chemical engineering, such as membrane distillation for wastewater treatment, hydrogen production from reforming reactions via inorganic membrane and membrane photoassisted reactors, membrane desalination, gas/liquid phase membrane separation of CO2, and membrane filtration for the recovery of antioxidants from agricultural byproducts, contributing to valorization of the potentialities of membrane operations.

Crystal Chemistry of Zinc, Cadmium and Mercury

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ISBN: 9783038976523 Year: Pages: 156 DOI: 10.3390/books978-3-03897-653-0 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Organic Chemistry --- Chemistry (General) --- Science (General)
Added to DOAB on : 2019-04-05 10:34:31
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This book is a printed edition of the Special Issue Crystal Chemistry of Zinc, Cadmium and Mercury that was published in Crystals

Novel Membrane Technologies for Traditional Industrial Processes

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ISBN: 9783038977902 / 9783038977919 Year: Pages: 196 DOI: 10.3390/books978-3-03897-791-9 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Physics (General)
Added to DOAB on : 2019-08-28 11:21:27
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Through reading this book, you will obtain information on: (1) the main problems in air separation and natural gas treatment by membrane separation and how to solve them; (2) processes involving membranes and new membrane materials for the more economical utilization of bio-resources; (3) energy selection and membrane development for more expedient and stable harnessing of the natural osmosis phenomenon; (4) many excellent contributions about catalytic membrane bioreactors; (5) how to fine-tune the arrangement of aquaporins (i.e., proteins identified in biological cells) to achieve superior water treatment efficiency.

Solid Catalysts for the Upgrading of Renewable Sources

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ISBN: 9783038975724 Year: Pages: 226 DOI: 10.3390/books978-3-03897-573-1 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemistry (General) --- Science (General)
Added to DOAB on : 2019-04-05 11:07:22
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The use of solid catalysts for the upgrade of renewable sources gives the opportunity to combine the two main cores of green chemistry, that is, on the one hand, the set-up of sustainable processes and, on the other, the use of biomass-derived materials. Solid catalysts have taken on a leading role in traditional petrochemical processes and could represent a key tool in new biorefinery-driven technologies.

Small Scale Deformation using Advanced Nanoindentation Techniques

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ISBN: 9783038979661 / 9783038979678 Year: Pages: 168 DOI: 10.3390/books978-3-03897-967-8 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General)
Added to DOAB on : 2019-06-26 08:44:06
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Small scale mechanical deformations have gained a significant interest over the past few decades, driven by the advances in integrated circuits and microelectromechanical systems. One of the most powerful and versatile characterization methods is the nanoindentation technique. The capabilities of these depth-sensing instruments have been improved considerably. They can perform experiments in vacuum and at high temperatures, such as in-situ SEM and TEM nanoindenters. This allows researchers to visualize mechanical deformations and dislocations motion in real time. Time-dependent behavior of soft materials has also been studied in recent research works. This Special Issue on ""Small Scale Deformation using Advanced Nanoindentation Techniques""; will provide a forum for researchers from the academic and industrial communities to present advances in the field of small scale contact mechanics. Materials of interest include metals, glass, and ceramics. Manuscripts related to deformations of biomaterials and biological related specimens are also welcome. Topics of interest include, but are not limited to:

Coordination Chemistry of Silicon

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ISBN: 9783038976387 Year: Pages: 225 DOI: 10.3390/books978-3-03897-639-4 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General) --- Inorganic Chemistry
Added to DOAB on : 2019-03-08 11:42:05
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The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.

Keywords

silanetriols --- disiloxane tetrols --- silsesquioxanes --- condensation --- molecular cage --- platinum --- primary silane --- hydrido complex --- oxidative addition --- ligand-exchange reaction --- X-ray crystallography --- Si–Cl activation --- germylene --- digermene --- digermacyclobutadiene --- palladium --- cluster --- cyclic organopolysilane --- template --- bridging silylene ligand --- isocyanide --- hydrogen bonds --- silicon --- 2-silylpyrrolidines --- stereochemistry --- X-ray crystallography --- Baird’s rule --- computational chemistry --- excited state aromaticity --- Photostability --- dye-sensitized solar cell --- disilanylene polymer --- photoreaction --- surface modification --- TiO2 --- silylene --- germylene --- N-heterocyclic carbene --- oxidative addition --- siloxanes --- host-guest chemistry --- supramolecular chemistry --- main group coordination chemistry --- hydrogen bonding --- adsorption --- bond activation --- bonding analysis --- density functional theory --- distorted coordination --- molecular orbital analysis --- silicon surfaces --- disilene --- functionalization --- ?-electron systems --- silicon --- N-heterocyclic carbenes --- bromosilylenes --- silyliumylidenes --- dehydrobromination --- silicon cluster --- siliconoid --- nanoparticle --- computation --- silicon --- N-heterocyclic carbenes --- silyliumylidenes --- small molecule activation --- mechanistic insights --- organosilicon --- reductant --- N-Heterocyclic tetrylene --- salt-free --- germanium --- germanethione --- germathioacid chloride --- N-heterocyclic carbines --- ?-chloro-?-hydrooligosilane --- titanium --- ruthenium --- dehydrogenative alkoxylation --- cluster --- isomerization --- silicon --- siliconoid --- subvalent compounds --- AIM --- DFT --- intermetallic bond --- 29Si NMR spectroscopy --- X-ray diffraction

Effects of Mycotoxins on the Intestine

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ISBN: 9783038977827 9783038977834 Year: Pages: 262 DOI: 10.3390/books978-3-03897-783-4 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Medicine (General) --- Public Health
Added to DOAB on : 2019-05-09 17:16:14
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Mycotoxins are secondary metabolites produced by several fungal species. They can contaminate human food and animal feed, and have been a threat for thousands of years. The gastrointestinal tract is the first target when ingesting mycotoxin-contaminated food or feed. As unlikely as it sounds, the investigations concerning the effects of mycotoxins on the intestine are still in their early stages. This book gathers the most recent advances related to the characterization of the intestinal toxicity of mycotoxins. Substantial data assembled on the damage caused to a number of histological structures and functions of the intestine remove any remaining doubt about this organ being a primary target for the toxicity of mycotoxins. An interesting overview of the detrimental effects of mycotoxins on the gut-hosted microbiota&mdash;now regarded as a fully-fledged organ associated with the gut&mdash;is also given. Finally, outstanding contributions in this book address questions relating to the suitability of current regulations to protect against alterations of the intestine, and to the efficacy assessment of new detoxification strategies using the intestinal toxicity of mycotoxins as a relevant endpoint.

Keywords

mice --- aflatoxin B1 --- intestinal bacterial flora --- response --- Clostridium sp. WJ06 --- deoxynivalenol --- pig --- intestinal morphology --- microbial diversity --- aflatoxin M1 --- ochratoxin A --- intestinal epithelial cells --- tight junction --- permeability --- ileum --- jejunum --- deoxynivalenol --- piglet --- contaminated feed --- tight junction --- aflatoxin B1 --- small intestine --- histopathological lesions --- ultrastructural changes --- toll-like receptors --- T-2 toxin --- enteric nervous system --- pig --- vasoactive intestinal polypeptide --- mycotoxins --- zearalenone --- deoxynivalenol --- histology --- ultrastructure --- large intestine --- pig --- Claviceps --- liver --- digestive tract --- mycotoxin --- sclerotia --- ergot alkaloids --- toxicity --- deoxynivalenol --- Saccharomyces cerevisiae boulardii CNCM I-1079 --- intestine --- transcriptome --- inflammation --- oxidative stress --- lipid metabolism --- fumonisin --- microbiota --- pigs --- MiSeq 16S rDNA sequencing --- intestinal microbiota --- hydrogen-rich water --- lactulose --- Fusarium mycotoxins --- piglets --- functional oligosaccharides --- mycotoxins --- swine --- explant technique --- intestinal morphology --- goblet cells --- deoxynivalenol --- zearalenone --- pig --- colon microbiota --- Lactobacillus --- detoxification --- zearalenone --- doses --- caecal water --- genotoxicity --- pre-pubertal gilts --- atlantic salmon --- deoxynivalenol --- feed --- intestine --- PCR --- proliferating cell nuclear antigen --- suppressor of cytokine signaling --- tight junctions --- Zearalenone --- N-acetylcysteine --- SIEC02 cells --- Mitochondrial apoptosis --- n/a

Titanium Dioxide Photocatalysis

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ISBN: 9783038976943 / 9783038976950 Year: Pages: 208 DOI: 10.3390/books978-3-03897-695-0 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General)
Added to DOAB on : 2019-06-26 08:44:06
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Although the seminal work of Fujishima et al. dates back to 1971, TiO2 still remains the most diffused and studied semiconductor, employed in photo-oxidation processes for cleantech (i.e., polluted water and air treatment), in solar fuel production (mainly hydrogen production by water photo splitting), and in Carbon Capture and Utilization (CCU) processes by CO2 photoreduction. The eleven articles, among them three reviews, in this book cover recent results and research trends of various aspects of titanium dioxide photocatalysis, with the chief aim of improving the final efficiency of TiO2-based materials. Strategies include doping, metal co-catalyst deposition, and the realization of composites with plasmonic materials, other semiconductors, and graphene. Photocatalysts with high efficiency and selectivity can be also obtained by controlling the precise crystal shape (and homogeneous size) and the organization in superstructures from ultrathin films to hierarchical nanostructures. Finally, the theoretical modeling of TiO2 nanoparticles is discussed and highlighted. The range of topics addressed in this book will stimulate the reader’s interest as well as provide a valuable source of information for researchers in academia and industry.

Biofuel and Bioenergy Technology

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ISBN: 9783038975960 Year: Pages: 425 DOI: 10.3390/books978-3-03897-597-7 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2019-03-21 14:08:22
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The subject of this book is ""Biofuel and Bioenergy Technology"". It aims to publish high-quality review and research papers, addressing recent advances in biofuel and bioenergy. State-of-the-art studies of advanced techniques of biorefinery for biofuel production are also included. Research involving experimental studies, recent developments, and novel and emerging technologies in this field are covered. This book contains twenty-seven technical papers which cover diversified biofuel and bioenergy technology-related research that have shown critical results and contributed significant findings to the fields of biomass processing, pyrolysis, bio-oil and its emulsification; transesterification and biodiesel, gasification and syngas, fermentation and biogas/methane, bioethanol and alcohol-based fuels, solid fuel and biochar, and microbial fuel cell and power generation development. The published contents relate to the most important techniques and analyses applied in the biofuel and bioenergy technology.

Keywords

air-steam gasification --- equilibrium model --- tar --- energy exchange --- exergy efficiency --- bio-electro-Fenton microbial fuel cells (Bio-E-Fenton MFCs) --- wastewater --- photo catalyst --- degradation --- calcination --- chemical oxygen demand (COD) --- MFC --- hydrodynamic boundary layer --- recirculation mode --- shear rate --- voltage --- charge transfer resistance --- biodiesel --- direct transesterification --- Rhodotorula glutinis --- single cell oil --- biogas --- tri-reforming process --- syngas --- methane and carbon dioxide conversion --- hydrogen/carbon monoxide ratio --- first-law/second-law efficiency --- biodiesel --- esterification --- liquid lipase --- superabsorbent polymer --- response surface methodology --- waste wood --- torrefaction --- energy yield --- mass yield --- CHO index --- gross calorific value --- Van Krevelen diagram --- anaerobic digestion --- biogas production --- wastewater treatment --- membrane bioreactors --- anaerobic digestion --- methane --- carbon dioxide --- small-scale biogas plants --- developing countries --- SOFC --- validation --- simulation --- exergy --- syngas --- Chlorella --- coal-fired flue-gas --- screening --- biodiesel property --- mixotrophic cultivation --- thermophilic anaerobic digestion --- corn stover --- prairie cord grass --- unbleached paper --- digester performance --- process stability --- synergistic effects --- microbial community --- Methanothermobacter --- biochemical methane potential --- redox potential reduction --- direct interspecies electron transfer --- electroactive biofilm --- Nejayote --- granular activated carbon --- Jerusalem artichoke --- lignocellulose --- acid pretreatment --- nitric acid --- alkali pretreatment --- enzymatic hydrolysis --- ethanol fermentation --- waste biomass --- Vietnam --- solid biofuel --- calorific value --- mechanical durability --- fatty acid methyl ester --- catalyst --- viscosity --- iodine value --- acidity index --- sewage sludge --- pyrolytic oil --- Taguchi method --- thermogravimetric analysis --- synergistic effect --- combined pretreatment --- ball mill --- ethanol organosolv --- herbaceous biomass --- lignin recovery --- Annona muricata --- biodiesel production --- seed oil --- soursop --- two-step process --- response surface methodology --- RSM --- second-generation biodiesel --- stone fruit --- optimisation --- biodiesel testing --- transesterification --- lignocellulosic biomass --- Miscanthus --- mechanical pretreatment --- organosolv pretreatment --- microbial biofuel --- metabolic engineering --- alkanes --- alcohols --- acetone --- electrochemical hydrogenation --- isopropanol --- membrane contamination --- polymer electrolyte membrane --- relative humidity --- diesel --- Carica papaya --- engine performance --- biodiesel --- characterisation --- porosity --- thermophoretic force --- biomass fuel --- non-premixed combustion --- counter-flow structure --- mathematical modeling --- emulsification --- liquefaction --- bio-oils --- co-surfactant --- surfactant --- diesel --- biogas --- Clostridiales --- hydrogen-producing bacteria --- bioreactors --- anaerobic fermentation --- anaerobic digestion --- microbial community composition

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eng (11)


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2019 (11)