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Subspace-Identification zur Modellierung von PEM-Brennstoffzellen-Stacks

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Book Series: Schriften des Instituts für Regelungs- und Steuerungssysteme, Karlsruher Institut für Technologie / Institut für Regelungs- und Steuerungssysteme ISSN: 18626688 ISBN: 9783866444775 Year: Volume: 7 Pages: xvi, 240 p. DOI: 10.5445/KSP/1000015691 Language: GERMAN
Publisher: KIT Scientific Publishing
Subject: Technology (General)
Added to DOAB on : 2019-07-30 20:02:02
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Der theoretische Schwerpunkt dieser Arbeit liegt in einem Vergleich und einer einheitlichen Beschreibung der in der Literatur existierenden Subspace-Identification-Verfahren. Im Anwendungsteil kommen diese zum Einsatz, um PEM-Brennstoffzellen-Stacks in einem für die Anwendung im Automobil relevanten Betriebsbereich nachbilden. Es werden außerdem zwei modellbasierte Ansätze vorgestellt, mit denen im Automobil nicht messbare Eingangsgrößen des Stacks geschätzt werden können.

Graphene and Other 2D Layered Nanomaterial-Based Films: Synthesis, Properties and Applications

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ISBN: 9783039219025 / 9783039219032 Year: Pages: 138 DOI: 10.3390/books978-3-03921-903-2 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General) --- Organic Chemistry
Added to DOAB on : 2020-01-07 09:08:26
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This book is dedicated to highlighting some relevant advances in the field of thin films and coatings based on two-dimensional crystals and layered nanomaterials. Due to their layered structure, graphene and a variety of new 2D inorganic nanosystems, called “graphene analogues”, have all attracted tremendous interest due to their unprecedented properties/superior performance, and may find applications in many fields from electronics to biotechnology. These two-dimensional systems are ultrathin and, hence, tend to be flexible, also presenting distinctive and nearly intrinsic characteristics, including electronic, magnetic, optical, thermal conductivity, and superconducting properties. Furthermore, the combination of different structures and synergetic effects may open new and unprecedented perspectives, making these ideal advanced materials for multifunctional assembled systems. As far as the field of coatings is concerned, new layered nanostructures may offer unique and multifunctional properties, including gas barrier, lubricant, conductive, magnetic, photoactive, self-cleaning, and/or antimicrobial surfaces. This book contains new findings on the synthesis and perspectives of multifunctional films that are at the forefront of the science and coating technologies.

Electrochemical Surface Science: Basics and Applications

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ISBN: 9783039216420 / 9783039216437 Year: Pages: 398 DOI: 10.3390/books978-3-03921-643-7 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General) --- Inorganic Chemistry
Added to DOAB on : 2019-12-09 11:49:15
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Electrochemical surface science (EC-SS) is the natural advancement of traditional surface science (where gas–vacuum/solid interfaces are studied) to liquid (solution)/electrified solid interfaces. Such a merging between two different disciplines—i.e., surface science (SS) and electrochemistry—officially advanced ca. three decades ago. The main characteristic of EC-SS versus electrochemistry is the reductionist approach undertaken, inherited from SS and aiming to understand the microscopic processes occurring at electrodes on the atomic level. A few of the exemplary keystone tools of EC-SS include EC-scanning probe microscopies, operando and in situ spectroscopies and electron microscopies, and differential EC mass spectrometry (DEMS). EC-SS indirectly (and often unconsciously) receives a great boost from the requirement for rational design of energy conversion and storage devices for the next generation of energetic landscapes. As a matter of fact, the number of material science groups deeply involved in such a challenging field has tremendously expanded and, within such a panorama, EC and SS investigations are intimately combined in a huge number of papers. The aim of this Special Issue is to offer an open access forum where researchers in the field of electrochemistry, surface science, and materials science could outline the great advances that can be reached by exploiting EC-SS approaches. Papers addressing both the basic science and more applied issues in the field of EC-SS and energy conversion and storage materials have been published in this Special Issue.

Keywords

electrosynthesis --- switchable surfaces --- alkoxyamine surfaces --- redox monolayers --- porphyrins --- self-assembly --- surface nanostructures --- in situ EC-STM --- metal-electrolyte interface --- potential-dependent structures --- combined non-covalent control --- ECALE --- CdS --- silver single crystals --- alkanthiols --- SAMs --- EQCM --- AES --- polypyrrole --- diazonium salts --- flexible ITO --- adhesion --- redox properties --- X-ray absorption spectroscopy --- energy dispersive --- quick-XAS --- FEXRAV --- free electron laser --- electrochemistry --- photoelectrochemistry --- photochemistry --- pump &amp --- probe --- oxygen evolution reaction --- water splitting --- iridium --- thin-films --- spin-coating --- model systems --- electrocatalysts --- oxygen evolution reaction --- iridium --- nickel --- electrodeposition --- model catalyst --- water oxidation --- CO oxidation --- DFT --- hydrogen adsorption --- Pt–Ru catalysts --- ordered mesoporous carbons --- graphitization --- CO oxidation --- methanol oxidation --- direct methanol fuel cells --- electrocatalysis --- catalysts --- methanol oxidation reaction --- graphene --- DMFC --- Pt --- SOFC --- cathode --- XAFS --- in situ --- cobalt oxide --- water oxidation --- photo-electrochemistry --- hydroxyl radical --- electro-oxidation --- Lead OPD --- surface alloy --- XPS --- UPS --- EF-PEEM --- ORR --- Platinum --- PVDF --- PEMFC --- in situ ambient pressure XPS --- hard X rays --- photoelectron simulations --- solid/liquid interface --- TiO2 --- APTES --- Cu(111) --- electrochemical interface --- in-situ X-ray diffraction --- carbon nanofiber --- porous fiber --- electrospinning --- mesopore --- micropore --- porogen --- ammonia activation --- surface area --- methanol oxidation --- platinum single crystals --- pH and concentration effects --- adsorbed OH --- reduced graphene oxide --- electrophoretic deposition --- surface chemistry --- click chemistry --- gold --- palladium --- bimetallic alloy --- carbon nanofibers (CNFs) --- cyclic voltammetry (CV) --- Surface Modification --- Blackening of Steel --- Magnetite --- Corrosion Protection --- Auger-Electron Spectroscopy --- Ordered mesoporous carbon --- nitrogen doping --- cobalt-based electrocatalyst --- bifunctional oxygen electrode --- solvothermal method --- underpotential deposition (upd) --- Au --- Pt --- Pd --- nanoparticles --- cyclic voltammetry --- electrocatalysis --- operando --- near ambient pressure XPS --- scanning photoelectron microscopy --- solid oxide fuel cells --- surface science --- electrodeposited alloys --- CO electro-oxidation --- Pt single-crystal electrodes --- potential cycling --- potential stepping --- surface reconstruction --- electrocatalysis --- oxygen reduction --- ORR --- gas diffusion electrode --- platinum --- fuel cells --- thin-films --- benchmarking --- mass transport --- formic acid oxidation --- Au nanocrystals --- Pd thin films --- electrocatalysis --- d-band theory --- polymer --- silicon nanoparticles --- EPR spectroscopy --- photoconversion --- n/a

Modeling and Simulation of Energy Systems

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ISBN: 9783039215188 / 9783039215195 Year: Pages: 496 DOI: 10.3390/books978-3-03921-519-5 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2019-12-09 11:49:16
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Energy Systems Engineering is one of the most exciting and fastest growing fields in engineering. Modeling and simulation plays a key role in Energy Systems Engineering because it is the primary basis on which energy system design, control, optimization, and analysis are based. This book contains a specially curated collection of recent research articles on the modeling and simulation of energy systems written by top experts around the world from universities and research labs, such as Massachusetts Institute of Technology, Yale University, Norwegian University of Science and Technology, National Energy Technology Laboratory of the US Department of Energy, University of Technology Sydney, McMaster University, Queens University, Purdue University, the University of Connecticut, Technical University of Denmark, the University of Toronto, Technische Universität Berlin, Texas A&M, the University of Pennsylvania, and many more. The key research themes covered include energy systems design, control systems, flexible operations, operational strategies, and systems analysis. The addressed areas of application include electric power generation, refrigeration cycles, natural gas liquefaction, shale gas treatment, concentrated solar power, waste-to-energy systems, micro-gas turbines, carbon dioxide capture systems, energy storage, petroleum refinery unit operations, Brayton cycles, to name but a few.

Keywords

cogeneration --- process integration --- solar energy --- thermal storage --- desalination --- optimization --- naphtha recovery unit --- statistical model --- simulation --- optimization --- concentrating solar thermal --- CST --- concentrating solar power --- CSP --- parabolic trough --- PTC --- thermal storage --- industrial process heat --- hybrid solar --- power plants --- supervisory control --- dynamic simulation --- dynamic optimization --- optimal control --- post-combustion CO2 capture --- energy efficiency --- time-varying operation --- shale gas condensate --- process synthesis and design --- shale gas condensate-to-heavier liquids --- technoeconomic analysis --- supercritical carbon dioxide --- recompression cycle --- combined cycle --- efficiency --- organic Rankine cycle --- exergy loss --- second law efficiency --- auto thermal reformer --- palladium membrane hydrogen separation --- polymer electrolyte membrane fuel cell (PEMFC) --- multi-loop control --- nonsmooth modeling --- process simulation --- DMR liquefaction processes --- fuel cost minimization problem --- FCMP --- piecewise-linear function generation --- linearization --- natural gas transportation --- compressor modeling --- compressibility factor --- isentropic exponent --- friction factor --- demand response --- energy management --- energy storage --- optimal battery operation --- battery degradation --- micro gas turbine --- modelling --- diagnostics, gas path analysis, analysis by synthesis --- circulating fluidized bed boiler --- refuse derived fuel --- waste to energy --- dynamic modeling --- process control --- dynamic modeling --- process control --- load-following --- supercritical pulverized coal (SCPC) --- cycling --- time-delay --- smith predictor --- energy systems --- modeling and simulation --- multi-scale systems engineering --- sustainable process design --- energy economics --- top-down models --- hybrid Life Cycle Assessment --- oil and gas --- offshore wind --- combined cycle --- hybrid system --- kriging --- multi-objective optimisation --- solar PV --- wind power --- life cycle analysis --- energy storage --- multiphase equilibrium --- RK-ASPEN --- methyl-oleate --- biodiesel --- supercritical CO2 --- WHENS --- work and heat integration --- building blocks --- superstructure --- MINLP --- absorption refrigeration --- H2O-LiBr working pair --- double-effect system --- cost optimization --- nonlinear mathematical programming --- Organic Rankine Cycle (ORC) --- geothermal energy --- binary cycle --- R245fa --- R123 --- mixture ratio --- Dieng --- Indonesia --- modeling --- simulation --- energy --- energy systems --- process systems engineering --- optimization --- process design --- operations

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