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Influence of strain on the functionality of ink-jet printed thin films and devices on flexible substrates

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Book Series: Schriftenreihe des Instituts für Angewandte Materialien, Karlsruher Institut für Technologie ISSN: 21929963 ISBN: 9783731508533 Year: Volume: 77 Pages: X, 127 p. DOI: 10.5445/KSP/1000086125 Language: ENGLISH
Publisher: KIT Scientific Publishing
Subject: Technology (General)
Added to DOAB on : 2019-07-30 20:02:00
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Ink-jet printed devices on the flexible substrate are inexpensive and large area compatible as compared to rigid substrates. However, during fabrication and service they are subjected to complex strains, resulting in crack formation or delamination within the layers, affecting the device performance. Therefore, it is necessary to understand their failure mechanisms by correlating their electrical or structural properties with applied strain, supported by detailed microstructural investigations.

Compounds with Polar Metallic Bonding

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ISBN: 9783039210701 / 9783039210718 Year: Pages: 154 DOI: 10.3390/books978-3-03921-071-8 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General) --- Inorganic Chemistry
Added to DOAB on : 2019-08-28 11:21:27
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The Special Edition 'Compounds with Polar Metallic Bonding' is a collection of eight original research reports presenting a broad variety of chemical systems, analytical methods, preparative pathways and theoretical descriptions of bonding situations, with the common aim of understanding the complex interplay of conduction electrons in intermetallic compounds that possess different types of dipoles. Coulombic dipoles introduced by electronegativity differences, electric or magnetic dipoles, polarity induced by symmetry reduction—all the possible facets of the term 'polarity'—can be observed in polar intermetallic phases and have their own and, in most cases, unique consequences on the physical and chemical behaviour. Elucidation of the structure–property relationships in compounds with polar metallic bonding is a modern and growing scientific field which combines solid state physics, preparative chemistry, metallurgy, modern analytic methods, crystallography, theoretical calculations of the electronic state and many more disciplines.

Carbonates

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ISBN: 9783038977223 Year: Pages: 146 DOI: 10.3390/books978-3-03897-723-0 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Physics (General) --- Science (General)
Added to DOAB on : 2019-04-05 10:34:31
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This Special Issue is aimed at presenting the state of the art of the multidisciplinary science concerning all aspects of volcanic plumes, of relevance to the volcanology, climatology, atmospheric science, and remote sensing communities.

Crystal Growth of Multifunctional Borates and Related Materials

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ISBN: 9783038978381 9783038978398 Year: Pages: 116 DOI: 10.3390/books978-3-03897-839-8 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Physics (General)
Added to DOAB on : 2019-05-09 17:16:14
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Borate crystals are attractive for different technological applications because of their favorable physical and chemical properties like stability and high transparency, both high thermal and non-linear optical coefficients, making them ideal active media for highly efficient solid state lasers. In this Special Issue, different aspects of multifunctional borate crystals are discussed, including ortho- and oxyorthoborates and compounds with condensed anions, as well as their nonlinear optical and laser properties and piezoelectric characteristics. For this reason, complex investigations of the phase relationships in multi-component borate melts, the study of crystal growth conditions of novel high-temperature borates, and the development of the &ldquo;crystallization conditions, composition, structure, and properties&rdquo; concept will provide a scientific basis for growth technologies of high performance electronic and optical devices and components with a variety of industrial, medical and many other applications. In the meantime, these relationships can help to estimate the affinity of synthetic borate materials with their natural prototypes and structural analogues.

Ionic Liquid Crystals

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ISBN: 9783039210862 / 9783039210879 Year: Pages: 108 DOI: 10.3390/books978-3-03921-087-9 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- Chemical Engineering
Added to DOAB on : 2019-06-26 08:44:06
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In this book we have collected a series of state-of-the art papers written by specialists in the field of ionic liquid crystals (ILCs) to address key questions concerning the synthesis, properties, and applications of ILCs. New compounds exhibiting ionic liquid crystalline phases are presented, both of calamitic as well as discotic type. Their dynamic and structural properties have been investigated with a series of experimental techniques including differential scanning calorimetry, polarized optical spectroscopy, X-ray scattering, and nuclear magnetic resonance, impedance spectroscopy to mention but a few. Moreover, computer simulations using both fully atomistic and highly coarse-grained force fields have been presented, offering an invaluable microscopic view of the structure and dynamics of these fascinating materials.

Thermo-Mechanical Behaviour of Structural Lightweight Alloys

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ISBN: 9783039213870 / 9783039213887 Year: Pages: 128 DOI: 10.3390/books978-3-03921-388-7 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Physics (General)
Added to DOAB on : 2019-12-09 16:10:12
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The need to reduce the ecological footprint of water/land/air vehicles in this era of climate change requires pushing the limits regarding the development of lightweight structures and materials. This requires a thorough understanding of their thermomechanical behavior at several stages of the production chain. Moreover, during service, the response of lightweight alloys under the simultaneous influence of mechanical loads and temperature can determine the lifetime and performance of a multitude of structural components. The present Special Issue, comprising eight original research articles, is dedicated to disseminating current efforts around the globe aimed at advancing understanding of the thermomechanical behavior of structural lightweight alloys under processing or service conditions.

Synthesis and Applications of New Spin Crossover Compounds

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ISBN: 9783039213610 / 9783039213627 Year: Pages: 254 DOI: 10.3390/books978-3-03921-362-7 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Physics (General)
Added to DOAB on : 2019-12-09 11:49:15
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The crystal chemistry of spin crossover (SCO) behavior in coordination compounds can potentially be in association with smart materials—promising materials for applications as components of memory devices, displays, sensors and mechanical devices and, especially, actuators, such as artificial muscles. This Special Issue is devoted to various aspects of SCO and related research, comprising 18 interesting original papers on valuable and important SCO topics. Significant and fundamental scientific attention has been focused on the SCO phenomena in a wide research range of fields of fundamental chemical and physical and related sciences, containing the interdisciplinary regions of chemical and physical sciences related to the SCO phenomena. Coordination materials with bistable systems between the LS and the HS states are usually triggered by external stimuli, such as temperature, light, pressure, guest molecule inclusion, soft X-ray, and nuclear decay. Since the first Hofmann-like spin crossover (SCO) behavior in {Fe(py)2[Ni(CN)4]}n (py = pyridine) was demonstrated, this crystal chemistry motif has been frequently used to design Fe(II) SCO materials to enable determination of the correlations between structural features and magnetic properties.

Keywords

spin crossover --- spin transition --- cobalt(II) ion --- paramagnetic ligand --- aminoxyl --- switch --- mosaicity --- spin crossover --- X-ray diffraction --- fatigability --- single crystal --- phase transition --- structural disorder --- spin-crossover --- dinuclear triple helicate --- Fe(II) --- solvent effects --- metal dithiolene complexes --- [Au(dmit)2]?, [Au(dddt)2]? --- ion-pair crystals --- [Fe(III)(3-OMesal2-trien)]+ --- coordination complexes --- crystal structure --- magnetic properties --- magnetic susceptibility --- magnetization --- spin-crossover transition --- Fe(II) complex --- dipyridyl-N-alkylamine ligands --- high spin (HS) --- low spin (LS) --- spin cross-over (SCO) --- magnetic transition --- cobalt oxide --- spin polaron --- impurity effect --- spin-state crossover --- coordination polymer --- supramolecular isomerism --- spin crossover --- crystal engineering --- spin crossover --- X-ray absorption spectroscopy --- soft X-ray induced excited spin state trapping --- high spin --- spin-crossover --- LIESST effect --- hydrogen bonding --- ?-? interactions --- charge-transfer phase transition --- iron mixed-valence complex --- hetero metal complex --- dithiooxalato ligand --- substitution of 3d transition metal ion --- ferromagnetism --- dielectric response --- 57Fe Mössbauer spectroscopy --- Fe(III) coordination complexes --- hexadentate ligand --- Schiff base --- spin crossover --- UV-Vis spectroscopy --- SQUID --- EPR spectroscopy --- spin-crossover --- optical microscopy --- reaction diffusion --- spin crossover --- Fe(III) complex --- qsal ligand --- thermal hysteresis --- structure phase transition --- counter-anion --- solvate --- lattice energy --- optical conductivity spectrum --- spiral structure --- 1,2-bis(4-pyridyl)ethane --- supramolecular coordination polymer --- chiral propeller structure --- atropisomerism --- spin crossover --- iron(II) complexes --- C–H···? interactions --- magnetic properties --- thermochromism --- spin crossover --- linear pentadentate ligand --- iron(II) --- mononuclear --- 1,2,3-triazole --- crystal structure --- magnetic properties --- DFT calculation --- intermolecular interactions --- amorphous --- spin crossover --- Cu(II) complexes --- nitroxides --- phase transitions --- magnetostructural correlations --- iron (II), spin crossover --- X-ray diffraction --- coordination polymers --- n/a

Recent Advances in GPR Imaging

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ISBN: 9783039218103 / 9783039218110 Year: Pages: 216 DOI: 10.3390/books978-3-03921-811-0 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Physics (General) --- Geophysics and Geomagnetism
Added to DOAB on : 2019-12-09 11:49:16
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The Special Issue (SI) “Recent Advances in GPR Imaging” offers an up-to-date overview of state-of-the-art research activities dealing with the development of Ground Penetrating Radar (GPR) technology and its recent advances in imaging in the different fields of application. In fact, the advances experimented with over the last few decades with regard to the appearance of new GPR systems and the need to manage large amounts of data suggest an increasing interest in the development of new signal processing algorithms and modeling, as well as in the use of three-dimensional (3D) imaging techniques.

High Precision X-Ray Measurements

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ISBN: 9783039213177 / 9783039213184 Year: Pages: 144 DOI: 10.3390/books978-3-03921-318-4 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Physics (General)
Added to DOAB on : 2019-12-09 16:10:12
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Since their discovery in 1895, the detection of X-rays has had a strong impact on and various applications in several fields of science and human life. Impressive efforts have been made to develop new types of detectors and new techniques, aiming to obtain higher precision both in terms of energy and position. Depending on the applications, solid state detectors, microcalorimeters, and various types of spectrometers currently serve as the best options for spectroscopic and imaging detectors. Recent advancements in micron and meV precision have opened the door for groundbreaking applications in fundamental physics, medical science, astrophysics, cultural heritage, and several other fields. The aim of this Special Issue is to compile an overview, from different communities and research fields, of the most recent developments in X-ray detection and their possible impacts in various sectors, such as in exotic atom measurements, quantum physics studies, XRF, XES, EXAFS, plasma emission spectroscopy, monochromators, synchrotron radiation, telescopes, and space engineering. All the papers included in this Special Issue contribute to emphasizing the importance of X-ray detection in a very broad range of physics topics; most of these topics are covered by the published works, and several others are mentioned in the paper references, providing an interesting and very useful synopsis, from a variety of different communities and research fields, of the most recent developments in X-ray detection and their impact in fundamental research and societal applications.

Coordination Chemistry of Silicon

Author:
ISBN: 9783038976387 Year: Pages: 225 DOI: 10.3390/books978-3-03897-639-4 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General) --- Inorganic Chemistry
Added to DOAB on : 2019-03-08 11:42:05
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The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.

Keywords

silanetriols --- disiloxane tetrols --- silsesquioxanes --- condensation --- molecular cage --- platinum --- primary silane --- hydrido complex --- oxidative addition --- ligand-exchange reaction --- X-ray crystallography --- Si–Cl activation --- germylene --- digermene --- digermacyclobutadiene --- palladium --- cluster --- cyclic organopolysilane --- template --- bridging silylene ligand --- isocyanide --- hydrogen bonds --- silicon --- 2-silylpyrrolidines --- stereochemistry --- X-ray crystallography --- Baird’s rule --- computational chemistry --- excited state aromaticity --- Photostability --- dye-sensitized solar cell --- disilanylene polymer --- photoreaction --- surface modification --- TiO2 --- silylene --- germylene --- N-heterocyclic carbene --- oxidative addition --- siloxanes --- host-guest chemistry --- supramolecular chemistry --- main group coordination chemistry --- hydrogen bonding --- adsorption --- bond activation --- bonding analysis --- density functional theory --- distorted coordination --- molecular orbital analysis --- silicon surfaces --- disilene --- functionalization --- ?-electron systems --- silicon --- N-heterocyclic carbenes --- bromosilylenes --- silyliumylidenes --- dehydrobromination --- silicon cluster --- siliconoid --- nanoparticle --- computation --- silicon --- N-heterocyclic carbenes --- silyliumylidenes --- small molecule activation --- mechanistic insights --- organosilicon --- reductant --- N-Heterocyclic tetrylene --- salt-free --- germanium --- germanethione --- germathioacid chloride --- N-heterocyclic carbines --- ?-chloro-?-hydrooligosilane --- titanium --- ruthenium --- dehydrogenative alkoxylation --- cluster --- isomerization --- silicon --- siliconoid --- subvalent compounds --- AIM --- DFT --- intermetallic bond --- 29Si NMR spectroscopy --- X-ray diffraction

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