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The Electrochemical Oxidation of H2 and CO at Patterned Ni Anodes of SOFCs

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Book Series: Schriften des Instituts für Werkstoffe der Elektrotechnik, Karlsruher Institut für Technologie / Institut für Werkstoffe der Elektrotechnik ISSN: 18681603 ISBN: 9783866446861 Year: Volume: 20 Pages: XI, 144 p. DOI: 10.5445/KSP/1000023286 Language: ENGLISH
Publisher: KIT Scientific Publishing
Subject: Technology (General)
Added to DOAB on : 2019-07-30 20:01:58
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In this work, a deeper understanding of the electrochemical oxidation at SOFC anodes was gained by the experimental characterization of patterned Ni anodes in H2-H2O and CO-CO2 atmosphere. By high resolution data analysis, the Line Specific Resistance attributed to charge transfer and its dependencies on gas composition, temperature and polarization voltage were identified. Furthermore, the comparison of the performance of patterned and cermet anodes was enabled using a transmission line model.

Finite Element Method (FEM) Model and Performance Analysis of Solid Oxide Fuel Cells

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Book Series: Schriften des Instituts für Angewandte Materialien - Werkstoffe der Elektrotechnik, Karlsruher Institut für Technologie / Institut für Angewandte Materialien - Werkstoffe der Elektrotechnik ISSN: 23658029 ISBN: 9783731508953 Year: Volume: 36 Pages: XIII, 259 p. DOI: 10.5445/KSP/1000090508 Language: ENGLISH
Publisher: KIT Scientific Publishing
Subject: Technology (General)
Added to DOAB on : 2019-07-30 20:01:57
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This work presents a numerical FEM framework, capable of predicting SOFC performance under technically relevant, planar stack contacting conditions. A high level of confidence in the model predictions is supplied by using exclusively experimentally determined material/kinetic parameters and by a comprehensive validation. The presented model aids SOFC stack development by pre-evaluating possible material choices and design combinations for cells/interconnectors without any experimental effort.

Microbial Fuel Cells 2018

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ISBN: 9783039215355 / 9783039215348 Year: Pages: 84 DOI: 10.3390/books978-3-03921-534-8 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering --- Environmental Engineering
Added to DOAB on : 2019-12-09 11:49:15
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The rapid growth of global energy consumption and simultaneous waste discharge requires more sustainable energy production and waste disposal/recovery technology. In this respect, microbial fuel cell and bioelectrochemical systems have been highlighted to provide a platform for waste-to-energy and cost-efficient treatment. Microbial fuel cell technology has also contributed to both academia and industry through the development of breakthrough sustainable technologies, enabling cross- and multi-disciplinary approaches in microbiology, biotechnology, electrochemistry, and bioprocess engineering. To further spread these technologies and to help the implementation of microbial fuel cells, this Special Issue, entitled “Microbial Fuel Cells 2018”, was proposed for the international journal Energies. This Special Issue mainly covers original research and studies related to the above-mentioned topic, including, but not limited to, bioelectricity generation, microbial electrochemistry, useful resource recovery, system and process design, and the implementation of microbial fuel cells.

Wide Bandgap Semiconductor Based Micro/Nano Devices

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ISBN: 9783038978428 / 9783038978435 Year: Pages: 138 DOI: 10.3390/books978-3-03897-843-5 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering --- Electrical and Nuclear Engineering
Added to DOAB on : 2019-08-28 11:21:27
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While group IV or III-V based device technologies have reached their technical limitations (e.g., limited detection wavelength range or low power handling capability), wide bandgap (WBG) semiconductors which have band-gaps greater than 3 eV have gained significant attention in recent years as a key semiconductor material in high-performance optoelectronic and electronic devices. These WBG semiconductors have two definitive advantages for optoelectronic and electronic applications due to their large bandgap energy. WBG energy is suitable to absorb or emit ultraviolet (UV) light in optoelectronic devices. It also provides a higher electric breakdown field, which allows electronic devices to possess higher breakdown voltages. This Special Issue seeks research papers, short communications, and review articles that focus on novel synthesis, processing, designs, fabrication, and modeling of various WBG semiconductor power electronics and optoelectronic devices.

Keywords

optical band gap --- tungsten trioxide film --- annealing temperature --- electrochromism --- AlGaN/GaN HEMT --- DIBL effect --- channel length modulation --- power amplifier --- W band --- high electron mobility transistors --- high electron mobility transistor (HEMT) --- AlGaN/GaN --- ohmic contact --- regrown contact --- ammonothermal GaN --- power amplifier --- I–V kink effect --- AlGaN/GaN HEMT --- large signal performance --- 4H-SiC --- MESFET --- ultrahigh upper gate height --- power added efficiency --- harsh environment --- space application --- 1T DRAM --- wide-bandgap semiconductor --- high-temperature operation --- TCAD --- amorphous InGaZnO (a-IGZO) --- thin-film transistor (TFT) --- positive gate bias stress (PGBS) --- passivation layer --- characteristic length --- edge termination --- silicon carbide (SiC) --- junction termination extension (JTE) --- breakdown voltage (BV) --- Ku-band --- GaN high electron mobility transistor (HEMT) --- power amplifier --- asymmetric power combining --- amplitude balance --- phase balance --- micron-sized patterned sapphire substrate --- growth of GaN --- sidewall GaN --- flip-chip light-emitting diodes --- distributed Bragg reflector --- light output power --- external quantum efficiency --- threshold voltage (Vth) stability --- gallium nitride (GaN) --- high electron mobility transistors (HEMTs) --- analytical model --- high-temperature operation --- T-anode --- GaN --- buffer layer --- anode field plate (AFP) --- cathode field plate (CFP) --- n/a

Thin Films for Energy Harvesting, Conversion, and Storage

Authors: --- ---
ISBN: 9783039217243 / 9783039217250 Year: Pages: 174 DOI: 10.3390/books978-3-03921-725-0 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- Chemical Engineering
Added to DOAB on : 2019-12-09 11:49:16
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Efficient clean energy harvesting, conversion, and storage technologies are of immense importance for the sustainable development of human society. To this end, scientists have made significant advances in recent years regarding new materials and devices for improving the energy conversion efficiency for photovoltaics, thermoelectric generation, photoelectrochemical/electrolytic hydrogen generation, and rechargeable metal ion batteries. The aim of this Special Issue is to provide a platform for research scientists and engineers in these areas to demonstrate and exchange their latest research findings. This thematic topic undoubtedly represents an extremely important technological direction, covering materials processing, characterization, simulation, and performance evaluation of thin films used in energy harvesting, conversion, and storage.

Clean Energy and Fuel (Hydrogen) Storage

Authors: ---
ISBN: 9783039216307 / 9783039216314 Year: Pages: 278 DOI: 10.3390/books978-3-03921-631-4 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2019-12-09 11:49:15
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Clean energy and fuel storage are often required for both stationary and automotive applications. Some of these clean energy and fuel storage technologies currently under extensive research and development include hydrogen storage, direct electric storage, mechanical energy storage, solar–thermal energy storage, electrochemical (batteries and supercapacitors), and thermochemical storage. The gravimetric and volumetric storage capacity, energy storage density, power output, operating temperature and pressure, cycle life, recyclability, and cost of clean energy or fuel storage are some of the factors that govern efficient energy and fuel storage technologies for potential deployment in energy harvesting (solar and wind farms) stations and onboard vehicular transportation. This Special Issue thus serves the need for promoting exploratory research and development on clean energy and fuel storage technologies while addressing their challenges to practical and sustainable infrastructures.

Keywords

dye-sensitized solar cells --- carbon materials --- Ag nanoparticles --- freestanding TiO2 nanotube arrays --- gas turbine engine --- lean direct injection --- four-point --- low emissions combustion --- carbonate gas reservoirs --- water invasion --- recovery factor --- aquifer size --- production rate --- hydrogen storage --- complex hydrides --- nanocatalyst --- LiNH2 --- MgH2 --- ball milling --- Li-ion batteries --- nanocomposite materials --- cathode --- anode --- binder --- separator --- ionic liquid --- vertically oriented graphene --- electrical double layers --- charge density --- capacitance --- gas storage --- material science --- rock permeability --- synthetic rock salt testing --- Klinkenberg method --- hydrogen storage systems --- hydrogen absorption --- thermochemical energy storage --- metal hydride --- magnetism --- heat transfer enhancement --- Power to Liquid --- Fischer–Tropsch --- dynamic modeling --- lab-scale --- lithium-ion batteries --- simplified electrochemical model --- state of charge estimator --- extended kalman filter --- hot summer and cold winter area --- PCM roof --- comprehensive incremental benefit --- conjugate phase change heat transfer --- lattice Boltzmann method --- large-scale wind farm --- auxiliary services compensation --- battery energy storage system --- optimal capacity --- equivalent loss of cycle life --- hydrogen storage --- porous media --- bacterial sulfate reduction --- methanogenesis --- gas loss --- diffusion --- reactive transport modeling --- PHREEQC --- energy discharge --- bubbles burst --- bubbles transportation --- crystal growth rates --- undercooling --- salt cavern --- leaching tubing --- flutter instability --- flow-induced vibration --- internal and reverse external axial flows --- thermal energy storage (TES) --- slag --- regenerator --- concentrated solar power (CSP) --- quality function deployment (QFD) --- failure mode and effect analysis (FMEA) --- thermal energy storage --- electrochemical energy storage --- hydrogen energy storage --- salt cavern energy storage

POSS-Based Polymers

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ISBN: 9783039219940 / 9783039219957 Year: Pages: 310 DOI: 10.3390/books978-3-03921-995-7 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2020-01-07 09:08:26
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Abstract

The combination of functional polymers with inorganic nanostructured compounds has become a major area of research and technological development owing to the remarkable properties and multifunctionalities deriving from their nano and hybrid structures. In this context, polyhedral oligomeric silsesquioxanes (POSSs) have increasing importance and a dominant position with respect to the reinforcement of polymeric materials. Although POSSs were first described in 1946 by Scott, these materials, however, have not immediately been successful if we consider that, starting from 1946 and up to 1995, we find in the literature 85 manuscripts regarding POSSs; which means that less than two papers per year were published over 50 years. Since 1995, we observe an exponential growth of scientific manuscripts concerning POSSs. It is changing from an annual average of 20 manuscripts for the period 1995–2000 to an annual average of about 400 manuscripts, with an increase of 2800%. The introduction of POSSs inorganic nanostructures into polymers gives rise to polymer nanostructured materials (PNMs) with interesting mechanical and physical properties, thus representing a radical alternative to the traditional filled polymers or polymer compositions.

Keywords

direct synthesis --- grafting synthesis --- mercapto-modified --- bridged silsesquioxane --- polyhedral oligomeric silsesquioxanes --- POSS --- composites --- thermal stability --- fluorescent sensors --- nitroaromatic explosives --- polyhedral oligomeric silsesquioxane-based ionic liquids --- self-assembly behaviors --- thiol-ene ‘click’ reaction --- siloxane-silsesquioxane resins --- polypropylene --- thermogravimetry --- cone calorimeter tests --- flame-retardant mechanism --- POSS --- filler --- low refractive material --- thermal stability --- fluoropolymer --- polyhedral oligomeric silsesquioxane (POSS) --- double-decker-shaped silsesquioxane (DDSQ) --- polyimide --- thermal stability --- dielectric constant --- poly(?-caprolactone) nanocomposite --- POSS nanoparticles --- dispersion --- morphology --- thermal properties --- mechanical properties --- surface properties --- phthalonitrile polymers --- phthalonitrile-polyhedral oligomeric silsesquioxane copolymers --- cyanate ester --- blends --- thermal properties --- POSS-based copolymer --- graphene oxide --- flame retardant --- epoxy resin --- giant surfactant --- thiol–ene “click” reaction --- polyhedral oligomeric silsesquioxane (POSS) --- poly(?-caprolactone) --- aqueous self-assembly --- POSS --- ridgid polyurethane foams --- mechanical properties --- cellular structure --- bi-functional POSS --- hydrophobic modification --- thermoplastic polyurethane --- mechanical performance --- silsesquioxanes --- optoelectronics --- OLEDs --- Monomethacryloxy POSS --- lauryl methacrylate --- polymerization kinetics --- anchor effect --- octa-ammonium POSS --- sodium alginate --- hydrogels --- temperature responsiveness --- Octavinyl-POSS --- organic-inorganic crosslinking --- Si@C anode --- lithium ion battery --- mechanism analysis --- monodisperse --- nanocomposites --- damping --- POSS --- liquefied --- benzoxazine --- POSS --- organic-inorganic hybrids --- epoxy resin --- thermal properties --- flame retardancy --- n/a

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