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Grain-size effects in nanoscaled electrolyte and cathode thin films for solid oxide fuel cells (SOFC)

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Book Series: Schriften des Instituts für Werkstoffe der Elektrotechnik, Universität Karlsruhe (TH) / Institut für Werkstoffe der Elektrotechnik ISSN: 18681603 ISBN: 9783866443365 Year: Volume: 15 Pages: VIII, 155 p. DOI: 10.5445/KSP/1000010126 Language: ENGLISH
Publisher: KIT Scientific Publishing
Subject: Technology (General)
Added to DOAB on : 2019-07-30 20:02:01
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Due to their high energy conversion efficiencies and low emissions, Solid Oxide Fuel Cells (SOFCs) show promise as a replacement for combustion-based electrical generators at all sizes. Further increase of SOFC efficiency can be achieved by microstructural optimization of the oxygen-ion conducting electrolyte and the mixed ionic-electronic conducting cathode. By application of nanoscaled thin films, the exceptionally high efficiency allows the realization of mobile SOFCs.

A novel micro-mechanical model for prediction of multiaxial high cycle fatigue at small scales

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Book Series: Schriftenreihe des Instituts für Angewandte Materialien, Karlsruher Institut für Technologie ISSN: 21929963 ISBN: 9783731505839 Year: Volume: 64 Pages: X, 112 p. DOI: 10.5445/KSP/1000059741 Language: ENGLISH
Publisher: KIT Scientific Publishing
Subject: Technology (General)
Added to DOAB on : 2019-07-30 20:02:01
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The grain microstructure and damage mechanisms at the grain level are the key factors that influence fatigue of metals at small scales. This is addressed in this work by establishing a new micro-mechanical model for prediction of multiaxial high cycle fatigue (HCF) at a length scale of 5-100?m. The HCF model considers elasto-plastic behavior of metals at the grain level and microstructural parameters, specifically the grain size and the grain orientation.

Special External Effects on Fluvial System Evolution

Authors: --- ---
ISBN: 9783039215447 / 9783039215454 Year: Pages: 200 DOI: 10.3390/books978-3-03921-545-4 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General)
Added to DOAB on : 2020-01-07 09:08:26
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Rivers are an excellent witness of the dynamics affecting Earth’s surface due to their sedimentary products and morphological expression, which may be considered as fluvial archives. Until now, the focus has been on evaluating the general impact of individual external factors. However, the importance of the specific environmental characteristics of these factors has become increasingly recognized, as highlighted in recent case studies. For example, the effects of regional climate, differentiated topography and vegetation, and frozen ground appear to play an essential role in the evolution of the fluvial system. Integration of such environmental conditions in the processes that were active within the complex fluvial system will open new perspectives in our progressive understanding of the evolution of landscape form, ecology, sediment fluxes, and hydrology of the system within the framework of the external drivers such as tectonics, general climate, and human activity. This is an appealing challenge that we wish to address in the present Special Issue under the aegis of the Fluvial Archives Group (FLAG).

Surface Modification to Improve Properties of Materials

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ISBN: 9783038977964 9783038977971 Year: Pages: 356 DOI: 10.3390/books978-3-03897-797-1 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2019-04-25 16:37:17
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This book contains selected contributions on surface modification to improve the properties of solid materials. The surface properties are tailored either by functionalization, etching, or deposition of a thin coating. Functionalization is achieved by a brief treatment with non-equilibrium gaseous plasma containing suitable radicals that interact chemically with the material surface and thus enable the formation of rather stable functional groups. Etching is performed in order to modify the surface morphology. The etching parameters are selected in such a way that a rich morphology of the surfaces is achieved spontaneously on the sub-micrometer scale, without using masks. The combination of adequate surface morphology and functionalization of materials leads to superior surface properties which are particularly beneficial for the desired response upon incubation with biological matter. Alternatively, the materials are coated with a suitable thin film that is useful in various applications from food to aerospace industries.

Keywords

sulphur hexafluoride (SF6) plasma --- tetrafluoromethane (CF4) plasma --- polymer polyethylene terephthalate (PET) --- surface modification --- functionalization and wettability --- optical emission spectroscopy (OES) --- electronegativity --- PVD nanocomposite coatings --- aluminum die casting --- tool life --- tribological performance --- plasma surface modification --- polymer polypropylene --- neutral oxygen atom density --- initial surface functionalization --- food packaging --- wettability --- tantalum --- hardness --- gradient nanostructured layer --- grain size --- residual stress --- dry wear behavior --- surface texture --- surface treatment --- Ti6Al4V alloy --- tribology --- biology --- materials characterization --- shot-peening --- image processing --- TIG welding --- aluminum 6061-T6 --- special surfaces --- wettability --- superhydrophobic --- cell cultures --- anti-bio adhesion --- self-cleaning fabrics --- polyethylene granules --- low-pressure MW air plasma --- optical emission spectroscopy --- XPS --- laser cobalt catalytic probe --- Alloy 718 --- surface hardness --- surface residual stress --- grain size --- fretting failure --- corrosion --- antimicrobial film --- nisin --- physical properties --- plasma treatment polyvinyl alcohol --- surface characterization --- microhole-textured tool --- CaF2 --- micro-EDM --- tribological properties --- egg shell --- stearic acid --- modification --- particle characterization --- epoxy composites --- dynamic mechanical analysis --- adhesion effectiveness --- Poly(tetrafluoroethylene) --- Teflon --- plasma treatment --- zeta potential --- surface energy --- contact angle measurement --- lectin --- bovine serum albumin --- adsorption --- cellulose thin film --- polystyrene --- gold --- surface plasmon resonance spectroscopy --- silver nanoparticles --- laser ablation in liquids --- laser synthesis of colloidal nanoparticles solution --- nanoparticle-impregnated paper --- antimicrobial activity --- fiber fines --- sheet forming --- vacuum filtration --- pulse power --- electrical stimulation --- electric field --- mushroom --- L. edodes --- Lyophyllum deeastes Sing --- surface modification --- porous silicon --- silicon surface --- carbonization --- oxidation --- aluminum --- alloy --- duralumin --- etching --- surface texture --- porous-like --- adhesive bonding --- superhydrophobic --- porous silicon --- visible light assisted organosilanization --- solid state NMR --- XPS --- ToF-SIMS --- atmospheric pressure plasma jets --- plasma polymerization --- superhydrophobicity --- wetting --- biomaterial --- polymer --- plasma --- functionalization --- surface properties --- thrombosis --- hemocompatibility --- endothealization --- vascular graft --- biocompatibility --- endothelial cells --- surface properties --- nanostructuring --- functionalization --- grafting

Earth Observation, Remote Sensing and Geoscientific Ground Investigations for Archaeological and Heritage Research

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ISBN: 9783039211937 / 9783039211944 Year: Pages: 304 DOI: 10.3390/books978-3-03921-194-4 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General)
Added to DOAB on : 2019-08-28 11:21:27
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This book collects 15 papers written by renowned scholars from across the globe that showcase the forefront research in Earth observation (EO), remote sensing (RS), and geoscientific ground investigations to study archaeological records and cultural heritage.Archaeologists, anthropologists, geographers, remote sensing, and archaeometry experts share their methodologies relying on a wealth of techniques and data including, but not limited to: very high resolution satellite images from optical and radar space-borne sensors, air-borne surveys, geographic information systems (GIS), archaeological fieldwork, and historical maps.A couple of the contributions highlight the value of noninvasive and nondestructive laboratory analyses (e.g., neutron diffraction) to reconstruct ancient manufacturing technologies, and of geological ground investigations to corroborate hypotheses of historical events that shaped cultural landscapes.Case studies encompass famous UNESCO World Heritage Sites (e.g., the Nasca Lines in Peru), remote and yet-to-discover archaeological areas in tropical forests in central America, European countries, south Asian changing landscapes, and environments which are arid nowadays but were probably full of woody vegetation in the past.Finally, the reader can learn about the state-of-the-art of education initiatives to train site managers in the use of space technologies in support of their activities, and can understand the legal aspects involved in the application of EO and RS to address current challenges of African heritage preservation.

Keywords

analytic hierarchy process (AHP) --- archaeology --- predictive model --- tumuli --- remote sensing --- multi-criteria --- Saharan Morocco --- airborne laser scanning --- orthophotographs --- archaeological survey --- field reconnaissance --- Arran --- national archaeological mapping programme --- synthetic aperture radar --- subsurface imaging --- microwave penetration --- archaeology --- arid environments --- remote sensing --- Oman --- e-learning --- Earth observation --- education --- capacity development --- cultural and natural heritage --- UNESCO --- photogrammetry --- RPAS --- UAV --- Peru --- geoglyph Pista --- mapping --- drones --- remote sensing --- free satellite imagery --- GoogleEarth --- Bing Maps --- archaeological fieldwork --- arid environments --- basalt desert --- landscape accessibility --- Harra --- Jordan --- archaeological landscapes --- settlements --- historical maps --- Survey of India --- Archaeological Survey of India --- heritage --- colonial studies --- remote sensing --- historical landscapes --- landscape archaeology --- settlements --- colonial studies --- river morphology --- Indus --- floods --- remote sensing --- satellite --- Sentinel-2 --- surface survey --- Roman archaeology --- Sumerian pottery --- neutron techniques --- neutron diffraction --- chemometric analysis --- Mega El Niño --- pampa of Nazca --- Cuenca Pisco --- Rio Grande de Nazca --- grain-size --- volcaniclastic layer --- stratigraphy --- petrography --- Lidar --- GIS --- Mesoamerica --- Archaeology --- Caves --- Landscape --- Ritual --- Visualization --- Maya --- Belize --- Sacred --- automated detection --- OBIA --- LiDAR --- Difference Map --- field monument --- Burial Mound --- Motte-and-Bailey castle --- Ridge and Furrow --- space law --- disaster and conservation management --- Geographic Information System (GIS) --- international boundaries --- Africa --- Cameroon-Nigeria Mixed Commission --- satellite imagery --- Boundary Demarcation --- international law --- relict boundaries --- Earth Observation --- remote sensing --- optical --- SAR --- drone --- airborne LiDAR --- GIS --- OBIA --- neutron diffraction --- archaeological prospection --- pattern recognition --- archaeometry --- geological mapping

Fluid Flow in Fractured Porous Media

Authors: ---
ISBN: 9783039214235 / 9783039214242 Year: Volume: 1 Pages: 578 DOI: 10.3390/books978-3-03921-424-2 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2019-12-09 11:49:15
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Abstract

The fluid flow in fracture porous media plays a significant role in the assessment of deep underground reservoirs, such as through CO2 sequestration, enhanced oil recovery, and geothermal energy development. Many methods have been employed—from laboratory experimentation to theoretical analysis and numerical simulations—and allowed for many useful conclusions. This Special Issue aims to report on the current advances related to this topic. This collection of 58 papers represents a wide variety of topics, including on granite permeability investigation, grouting, coal mining, roadway, and concrete, to name but a few. We sincerely hope that the papers published in this Special Issue will be an invaluable resource for our readers.

Keywords

scanning electron microscope (SEM) images --- permeability --- high temperature --- Darcy’s law --- confining pressures --- chemical grouts --- grain size of sand --- initial water contained in sand --- grouted sand --- macroscopic mechanical behaviors --- microstructure characteristics --- ductile failure --- gas concentration --- gob-side entry retaining (GER) --- limestone roof --- roof-cutting resistance --- roadside backfill body (RBB) --- solid backfill coal mining --- goaf --- water soaked height --- loose gangue backfill material --- deformation --- crushing ratio --- fracture grouting --- cement–silicate grout --- geophysical prospecting --- seepage --- Yellow River Embankment --- contiguous seams --- water-dripping roadway --- roadway deformation --- bolt support --- pervious concrete --- permeability coefficient --- porosity --- pore distribution characteristics --- strength --- soil–structure interface --- internal erosion --- critical hydraulic gradient --- orthogonal tests --- Pseudo Steady-State (PPS) constant --- finite-conductivity fracture --- conductivity-influence function --- normalized conductivity-influence function --- circular closed reservoir --- glutenite --- gravel --- hydraulic fracture --- numerical simulation --- propagation --- glauberite cavern for storing oil &amp --- gas --- thermal-hydrological-chemical interactions --- temperature --- brine concentration --- microstructure --- micro-CT --- damage --- cyclic heating and cooling --- physical and mechanical parameters --- failure mode --- acoustic emission --- anisotropy --- bedding plane orientation --- coal --- gas --- adsorption–desorption --- laboratory experiment --- pore pressure --- hydro-mechanical coupling --- fracture closure --- constitutive model --- effective stress --- debris flow --- dynamic characteristics --- numerical analysis --- debris-resisting barriers --- coal measures sandstone --- creep characteristics --- seepage pressure --- seepage-creep --- microscopic morphology --- Darcy flow --- heterogeneity --- numerical manifold method --- high-order --- refraction law --- hydraulic fracture network --- cohesive element method --- coal seams --- fracture propagation --- discontinuous natural fracture --- secondary fracture --- fault water inrush --- coupled THM model --- nonlinear flow in fractured porous media --- numerical model --- warning levels of fault water inrush --- bentonite-sand mixtures --- differential settlement --- deformation --- hydraulic conductivity --- crack --- geogrid --- enhanced permeability --- deviatoric stress --- mechanical behavior transition --- CH4 seepage --- volumetric strain --- strain-based percolation model --- rock-soil mechanics --- soft filling medium --- segmented grouting --- split grouting --- model experiment --- reinforcement mechanism --- longwall mining --- gob behaviors --- stress relief --- permeability --- gas drainage --- hard and thick magmatic rocks --- orthogonal ratio test --- similar simulation --- fracture --- bed separation --- disaster-causing mechanism --- artificial joint rock --- shear-flow coupled test --- hydraulic aperture --- roughness --- seepage pressure --- mixing --- conservative solute --- fractal --- roughness --- fracture --- transversely isotropic rocks --- failure mechanism --- particle flow modeling --- interface --- n/a --- fractured porous rock mass --- grouting experiment --- visualization system --- flow law --- layered progressive grouting --- sandstone and mudstone particles --- rheological deformation --- segmented rheological model --- rheological limit strain --- rheological test --- water-rock interaction --- dry-wet cycles --- slope stability --- laboratory experiment --- mechanical properties --- Xinjiang --- land reclamation --- management period --- soil particle size --- fluid flow in reclaimed soil --- effluents --- soil properties --- cohesive soils --- contamination --- time variation --- stabilization --- mixer --- viscoelastic fluid --- pore structure --- orthogonal test --- fluid–solid coupling theory --- similar-material --- regression equation --- optimum proportioning --- hydraulic fracturing --- gas fracturing --- oriented perforation --- fracture propagation --- damage mechanics --- fluid viscosity --- CO2 flooding --- supercritical CO2 --- CO2 geological storage --- tight sandstone gas reservoirs --- enhanced gas recovery --- flotation --- coal particle --- collision angle --- initial settlement position --- particle velocity --- adhesion efficiency --- green mining --- paste-like slurry --- XRD --- intelligent torque rheometer --- on-site monitoring --- cyclic wetting-drying --- deterioration --- sandstone --- mudstone --- elastic modulus --- uniaxial compressive strength --- permeability characteristics --- grading broken gangue --- compressive stress --- compression deformation --- mine shaft --- alternate strata --- surrounding rock --- shaft lining --- relief excavation --- consolidation process --- unsaturated soil --- semi-analytical solution --- impeded drainage boundary --- excess pore-pressures --- coalbed methane (CBM) --- soft coal masses --- pore structure --- fractal pore characteristics --- hydraulic fractures --- PPCZ --- multitude parameters --- propagation pattern --- stress interference --- naturally fracture --- filtration effects --- grout penetration --- unified pipe-network method --- two-phase flow --- fractured porous medium --- new cementitious material --- cement-based paste discharge --- XRD --- TG/DTG --- SEM --- MIP --- mechanical behaviors --- rock fracture --- shear-flow coupled test --- constant normal stiffness conditions --- transmissivity --- hydraulic aperture --- water inrush prevention --- backfill mining --- strata movement --- ground pressure --- floor failure depth --- water–rock interaction --- degradation mechanism --- mixed mode fracture resistance --- fracture criteria --- T-stress --- hydro-power --- high-steep slope --- fractured rock --- permeability --- seepage control --- gas-bearing coal --- electrical potential --- charge separation --- gas adsorption --- damage evolution --- Unsaturation --- chloride --- concrete --- coupling model --- numerical calculation --- debris flow --- forecasting --- rainfall-unstable soil coupling mechanism(R-USCM) --- scoops3D --- Jiaohe --- non-aqueous phase liquid --- finite element method --- two-phase flow --- mixed-form formulation --- FLAC --- pore structure --- movable fluid --- tight sandstones --- Ordos Basin --- tectonically deformed coal --- coal and gas outburst --- coal-like material --- mechanical properties --- deformation feature --- adsorption/desorption properties --- minerals --- mechanical properties --- uniaxial compressive strength --- crack distribution characteristics --- discrete element method --- lignite --- nitric acid modification --- pore structure --- surface characteristics --- adsorption performance --- n/a

Fluid Flow in Fractured Porous Media

Authors: ---
ISBN: 9783039214730 / 9783039214747 Year: Volume: 2 Pages: 492 DOI: 10.3390/books978-3-03921-474-7 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2019-12-09 11:49:15
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Abstract

The fluid flow in fracture porous media plays a significant role in the assessment of deep underground reservoirs, such as through CO2 sequestration, enhanced oil recovery, and geothermal energy development. Many methods have been employed—from laboratory experimentation to theoretical analysis and numerical simulations—and allowed for many useful conclusions. This Special Issue aims to report on the current advances related to this topic. This collection of 58 papers represents a wide variety of topics, including on granite permeability investigation, grouting, coal mining, roadway, and concrete, to name but a few. We sincerely hope that the papers published in this Special Issue will be an invaluable resource for our readers.

Keywords

scanning electron microscope (SEM) images --- permeability --- high temperature --- Darcy’s law --- confining pressures --- chemical grouts --- grain size of sand --- initial water contained in sand --- grouted sand --- macroscopic mechanical behaviors --- microstructure characteristics --- ductile failure --- gas concentration --- gob-side entry retaining (GER) --- limestone roof --- roof-cutting resistance --- roadside backfill body (RBB) --- solid backfill coal mining --- goaf --- water soaked height --- loose gangue backfill material --- deformation --- crushing ratio --- fracture grouting --- cement–silicate grout --- geophysical prospecting --- seepage --- Yellow River Embankment --- contiguous seams --- water-dripping roadway --- roadway deformation --- bolt support --- pervious concrete --- permeability coefficient --- porosity --- pore distribution characteristics --- strength --- soil–structure interface --- internal erosion --- critical hydraulic gradient --- orthogonal tests --- Pseudo Steady-State (PPS) constant --- finite-conductivity fracture --- conductivity-influence function --- normalized conductivity-influence function --- circular closed reservoir --- glutenite --- gravel --- hydraulic fracture --- numerical simulation --- propagation --- glauberite cavern for storing oil &amp --- gas --- thermal-hydrological-chemical interactions --- temperature --- brine concentration --- microstructure --- micro-CT --- damage --- cyclic heating and cooling --- physical and mechanical parameters --- failure mode --- acoustic emission --- anisotropy --- bedding plane orientation --- coal --- gas --- adsorption–desorption --- laboratory experiment --- pore pressure --- hydro-mechanical coupling --- fracture closure --- constitutive model --- effective stress --- debris flow --- dynamic characteristics --- numerical analysis --- debris-resisting barriers --- coal measures sandstone --- creep characteristics --- seepage pressure --- seepage-creep --- microscopic morphology --- Darcy flow --- heterogeneity --- numerical manifold method --- high-order --- refraction law --- hydraulic fracture network --- cohesive element method --- coal seams --- fracture propagation --- discontinuous natural fracture --- secondary fracture --- fault water inrush --- coupled THM model --- nonlinear flow in fractured porous media --- numerical model --- warning levels of fault water inrush --- bentonite-sand mixtures --- differential settlement --- deformation --- hydraulic conductivity --- crack --- geogrid --- enhanced permeability --- deviatoric stress --- mechanical behavior transition --- CH4 seepage --- volumetric strain --- strain-based percolation model --- rock-soil mechanics --- soft filling medium --- segmented grouting --- split grouting --- model experiment --- reinforcement mechanism --- longwall mining --- gob behaviors --- stress relief --- permeability --- gas drainage --- hard and thick magmatic rocks --- orthogonal ratio test --- similar simulation --- fracture --- bed separation --- disaster-causing mechanism --- artificial joint rock --- shear-flow coupled test --- hydraulic aperture --- roughness --- seepage pressure --- mixing --- conservative solute --- fractal --- roughness --- fracture --- transversely isotropic rocks --- failure mechanism --- particle flow modeling --- interface --- n/a --- fractured porous rock mass --- grouting experiment --- visualization system --- flow law --- layered progressive grouting --- sandstone and mudstone particles --- rheological deformation --- segmented rheological model --- rheological limit strain --- rheological test --- water-rock interaction --- dry-wet cycles --- slope stability --- laboratory experiment --- mechanical properties --- Xinjiang --- land reclamation --- management period --- soil particle size --- fluid flow in reclaimed soil --- effluents --- soil properties --- cohesive soils --- contamination --- time variation --- stabilization --- mixer --- viscoelastic fluid --- pore structure --- orthogonal test --- fluid–solid coupling theory --- similar-material --- regression equation --- optimum proportioning --- hydraulic fracturing --- gas fracturing --- oriented perforation --- fracture propagation --- damage mechanics --- fluid viscosity --- CO2 flooding --- supercritical CO2 --- CO2 geological storage --- tight sandstone gas reservoirs --- enhanced gas recovery --- flotation --- coal particle --- collision angle --- initial settlement position --- particle velocity --- adhesion efficiency --- green mining --- paste-like slurry --- XRD --- intelligent torque rheometer --- on-site monitoring --- cyclic wetting-drying --- deterioration --- sandstone --- mudstone --- elastic modulus --- uniaxial compressive strength --- permeability characteristics --- grading broken gangue --- compressive stress --- compression deformation --- mine shaft --- alternate strata --- surrounding rock --- shaft lining --- relief excavation --- consolidation process --- unsaturated soil --- semi-analytical solution --- impeded drainage boundary --- excess pore-pressures --- coalbed methane (CBM) --- soft coal masses --- pore structure --- fractal pore characteristics --- hydraulic fractures --- PPCZ --- multitude parameters --- propagation pattern --- stress interference --- naturally fracture --- filtration effects --- grout penetration --- unified pipe-network method --- two-phase flow --- fractured porous medium --- new cementitious material --- cement-based paste discharge --- XRD --- TG/DTG --- SEM --- MIP --- mechanical behaviors --- rock fracture --- shear-flow coupled test --- constant normal stiffness conditions --- transmissivity --- hydraulic aperture --- water inrush prevention --- backfill mining --- strata movement --- ground pressure --- floor failure depth --- water–rock interaction --- degradation mechanism --- mixed mode fracture resistance --- fracture criteria --- T-stress --- hydro-power --- high-steep slope --- fractured rock --- permeability --- seepage control --- gas-bearing coal --- electrical potential --- charge separation --- gas adsorption --- damage evolution --- Unsaturation --- chloride --- concrete --- coupling model --- numerical calculation --- debris flow --- forecasting --- rainfall-unstable soil coupling mechanism(R-USCM) --- scoops3D --- Jiaohe --- non-aqueous phase liquid --- finite element method --- two-phase flow --- mixed-form formulation --- FLAC --- pore structure --- movable fluid --- tight sandstones --- Ordos Basin --- tectonically deformed coal --- coal and gas outburst --- coal-like material --- mechanical properties --- deformation feature --- adsorption/desorption properties --- minerals --- mechanical properties --- uniaxial compressive strength --- crack distribution characteristics --- discrete element method --- lignite --- nitric acid modification --- pore structure --- surface characteristics --- adsorption performance --- n/a

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