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Linking Optical and Chemical Properties of Dissolved Organic Matter in Natural Waters

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Book Series: Frontiers Research Topics ISSN: 16648714 ISBN: 9782889450817 Year: Pages: 242 DOI: 10.3389/978-2-88945-081-7 Language: English
Publisher: Frontiers Media SA
Subject: Chemistry (General) --- Geography --- Oceanography --- Science (General)
Added to DOAB on : 2017-07-06 13:27:36
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A substantial increase in the number of studies using the optical properties (absorbance and fluorescence) of dissolved organic matter (DOM) as a proxy for its chemical properties in estuaries and the coastal and open ocean has occurred during the last decade. We are making progress on finding the actual chemical compounds or phenomena responsible for DOM’s optical properties. Ultrahigh resolution mass spectrometry, in particular, has made important progress in making the key connections between optics and chemistry. But serious questions remain and the last major special issue on DOM optics and chemistry occurred nearly 10 years ago. Controversies remain from the non-specific optical properties of DOM that are not linked to discrete sources, and sometimes provide conflicting information. The use of optics, which is relatively easier to employ in synoptic and high resolution sampling to determine chemistry, is a critical connection to make and can lead to major advances in our understanding of organic matter cycling in all aquatic ecosystems. The contentions and controversies raised by our poor understanding of the linkages between optics and chemistry of DOM are bottlenecks that need to be addressed and overcome.

Selenium Isotope Studies in Plants - Development and Validation of a Novel Geochemical Tool and its Application to Organic Samples

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Book Series: Karlsruher mineralogische und geochemische Hefte : Schriftenreihe des Instituts für Angewandte Geowissenschaften ISSN: 16182677 ISBN: 9783731505945 Year: Volume: 42 Pages: XXV, 223 p. DOI: 10.5445/KSP/1000060292 Language: ENGLISH
Publisher: KIT Scientific Publishing
Subject: Ethnology
Added to DOAB on : 2019-07-30 20:02:00
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Selenium (Se), being an essential nutrient and a toxin, enters the food chain mainly via plants. Selenium isotope signatures were proved to be an excellent redox tracer, making it a promising tool for the exploration of the Se cycle in plants. The analytical method is sensitive on organic samples and requires particular preparation methods, which were developed and validated in this study. Plant cultivation setups revealed the applicability of these methods to trace plant internal processes.

Polymetallic Metallogenic System

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ISBN: 9783039212934 / 9783039212941 Year: Pages: 538 DOI: 10.3390/books978-3-03921-294-1 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General)
Added to DOAB on : 2019-12-09 16:10:12
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Within the last decade, the high and continuing demand for precious and base metals, as well as critical elements, has prompted a global rush on a scale never before seen. This eventually resulted in the demand for considerable innovation and improvement in mineral deposit genetic modelling and ore formation regimes for the many different types of gold deposits, now recognized, and paralleled by the wide employment of exploration techniques and a rapid expansion of geological databases. This Special Issue will show case studies of porphyry polymetal systems, orogenic gold formations, water–rock reaction, ore-forming structure evolution, mineralogy and petrology of ore deposit, ore formation regime, geochronology and geochemistry of ore deposit, ore-forming evolution, mineral exploration and cutting-edge technology in ore deposit study.

Keywords

W–Sn skarn --- whole-rock geochemistry --- Huangshaping --- Shizhuyuan --- Xianghualing --- Rare-Earth Elements --- C–O isotopes --- hydrothermal calcite --- ore-forming processes --- Phapon gold deposit --- oxidation state --- hydrous melts --- constraints on mineralization --- Beiya Au deposit --- SW China --- zircon geochronology --- magmatic oxygen fugacity --- petrogenesis --- Zaozigou deposit --- West Qinling --- archean basement --- quartz vein --- hydrothermal alteration halo --- Pinglidian gold deposit --- Jiaodong --- geochemistry --- U–Pb zircon age --- Sr–Nd isotopes --- Haoyaoerhudong gabbro --- Inner Mongolia --- geochronology --- Hf isotopes --- petrogenesis --- paleo-Tethyan ocean closure --- Zaorendao gold deposit --- West Qinling --- syenite --- post-collisional --- niobium mineralization --- Saima deposit --- Liaoning Province --- invisible gold --- visible gold --- LA-ICP-MS --- Yangshan gold belt --- West Qinling --- zircon U-Pb dating --- molybdenite Re-Os dating --- zircon Hf isotopes --- Weilasituo Sn-polymetallic deposit --- Inner Mongolia --- orogenic-gold deposit --- mineral geo-thermometry --- physicochemical condition of mineralization --- Zhengchong gold deposit --- Jiangnan orogenic belt --- lithospheric architecture --- metallogenesis --- Hf-Nd isotopic mapping --- Liaodong Peninsula --- North China Craton --- zircon U–Pb geochronology --- Sr–Nd–Pb–Hf isotopes --- low Sr and high Yb A2-type granite --- Xianghualing --- South China --- fluid inclusion --- stable isotopes --- gold deposition --- Sanshandao gold deposit --- Jiaodong --- fluid inclusions --- H–O isotope --- immiscibility --- water–rock interaction --- Sizhuang gold deposit --- Jiaodong Peninsula --- China --- Pulang porphyry Cu (–Mo–Au) deposit --- LA-ICP-MS zircon U–Pb dating --- molybdenite Re–Os dating --- high-silica adakitic rocks (HSA) --- Northwestern Yunnan Province --- C–H–O isotopes --- fluid inclusion --- Koka deposit --- orogenic gold deposit --- ore shoots --- structural control --- geostatistics --- Sizhuang gold deposit --- Jiaodong Peninsula --- skarn mineralogy --- high fugacity --- garnet Sm–Nd dating --- Late Cretaceous --- Hongshan skarn deposit --- mantle branch --- metallogenesis --- ore-controlling structures --- metallogenic rule --- ore prospecting target --- Jiaodong area --- zircon U–Pb dating --- Re–Os dating --- middle–late Jurassic --- Mo-polymetallic deposit --- Great Xing’an Range --- Dongbulage --- A-type granite --- tin mineralization --- Tiantangshan tin polymetallic deposit --- SE China --- Chishan alkaline complex --- rock geochemistry --- zircon U–Pb dating --- Lu–Hf isotopes --- Hegenshan-Heihe suture zone --- Cu-Au hydrothermal mineralization --- Hongyan deposit --- Permian A-type granite --- granite petrogenesis --- magmatic oxygen fugacity --- post-collisional slab break-off --- quartz --- trace element --- precipitation mechanism --- in situ study --- sericite --- acidity --- formation temperature --- n/a

Wine Traceability

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ISBN: 9783039217687 / 9783039217694 Year: Pages: 138 DOI: 10.3390/books978-3-03921-769-4 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Biology --- Biochemistry
Added to DOAB on : 2019-12-09 11:49:16
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Wine traceability is a central theme in the current world market where consumers are increasingly demanding the quality and origin of food and drink. The wine production chain and wine composition are generally controlled by different laws (International Organization of Vine and Wine (OIV), European Union (EU), and national governments) and need specific documentation. Nevertheless, wine production is subject to fraud. Consequently, the improvement of the methods applied to verify the origin and quality of wines is very important to protect wine consumers and producers. In this book, eight different papers—six research papers and two reviews—address the topic from different points of view.

Volcanic Plumes.Impacts on the Atmosphere and Insights into Volcanic Processes

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ISBN: 9783038976288 Year: Pages: 252 DOI: 10.3390/books978-3-03897-629-5 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General)
Added to DOAB on : 2019-04-05 10:34:31
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Volcanoes release plumes of gas and ash to the atmosphere during episodes of passive and explosive behavior. These ejecta have important implications for the chemistry and composition of the troposphere and stratosphere, with the capacity to alter Earth's radiation budget and climate system over a range of temporal and spatial scales. Volcanogenic sulphur dioxide reacts to form sulphate aerosols, which increase global albedo, e.g., by reducing surface temperatures, in addition to perturbing the formation processes and optical properties of clouds. Released halogen species can also deplete stratospheric and tropospheric ozone. Volcanic degassing, furthermore, played a key role in the formation of Earth’s atmosphere, and volcanic plumes can affect air quality, pose hazards to aviation and human health, as well as damage ecosystems. The chemical compositions and emission rates of volcanic plumes are also monitored via a range of direct-sampling and remote-sensing instrumentation, in order to gain insights into subterranean processes, in the respect of the magmatic bodies these volatiles exsolve from. Given the significant role these gases play in driving volcanic activity, e.g., via pressurisation, the study of volcanic plumes is proving to be an increasingly fruitful means of improving our understanding of volcanic systems, potentially in concert with observations from geophysics and contributions from fluid dynamical modelling of conduit dynamics.

Mineral Surface Reactions at the Nanoscale

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ISBN: 9783038978961 / 9783038978978 Year: Pages: 220 DOI: 10.3390/books978-3-03897-897-8 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Geology --- Earth Sciences
Added to DOAB on : 2019-06-26 08:44:06
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Reactions at mineral surfaces are central to all geochemical processes. As minerals comprise the rocks of the Earth, the processes occurring at the mineral–aqueous fluid interface control the evolution of the rocks and hence the structure of the crust of the Earth during processes such as metamorphism, metasomatism, and weathering. In recent years focus has been concentrated on mineral surface reactions made possible through the development of advanced analytical methods such as atomic force microscopy (AFM), advanced electron microscopies (SEM and TEM), phase shift interferometry, confocal Raman spectroscopy, and advanced synchrotron-based applications, to enable mineral surfaces to be imaged and analyzed at the nanoscale. Experiments are increasingly complemented by molecular simulations to confirm or predict the results of these studies. This has enabled new and exciting possibilities to elucidate the mechanisms that govern mineral–fluid reactions. In this Special Issue, “Mineral Surface Reactions at the Nanoscale”, we present 12 contributions that highlight the role and importance of mineral surfaces in varying fields of research.

Preservation of Cultural Heritage and Resources Threatened by Climate Change

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ISBN: 9783039211241 / 9783039211258 Year: Pages: 186 DOI: 10.3390/books978-3-03921-125-8 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General)
Added to DOAB on : 2019-12-09 11:49:15
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With its wide spectrum of data, case studies, monitoring, and experimental and numerical simulation techniques, the multidisciplinary approach of material, environmental, and computer science applied to the conservation of cultural heritage offers several opportunities for the heritage science and conservation community to map and monitor state-of-the-art knowledge on natural and human-induced climate change impacts on cultural heritage—mainly constituted by the built environment—in Europe and Latin America. Geosciences’ Special Issue titled “Preservation of Cultural Heritage and Resources Threatened by Climate Change” was launched to take stock of the existing but still fragmentary knowledge on this challenge, and to enable the community to respond to the implementation of the Paris agreement. These 10 papers exploit a broad range of data derived from preventive conservation monitoring conducted indoors in museums, churches, historical buildings, or outdoors in archeological sites and city centers. Case studies presented in the papers focus on a well-assorted sample of decay phenomena occurring on heritage materials (e.g., surface recession and biomass accumulation on limestone, depositions of pollutant on marble, salt weathering on inorganic building materials, and weathering processes on mortars in many local- to regional-scale study areas in the Scandinavian Peninsula, the United Kingdom, Belgium, France, Italy, Greece, and Panama). Besides monitoring, the methodological approaches showcased include, but are not limited to, original material characterization, decay product characterization, and climate and numerical modelling on material components for assessing environmental impact and climate change effects.

Arctic Mineral Resources. Science and Technology

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ISBN: 9783038978244 9783038978251 Year: Pages: 432 DOI: 10.3390/books978-3-03897-825-1 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General)
Added to DOAB on : 2019-04-25 16:37:17
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The Arctic zone of the Earth is a major source of mineral and other natural resources for the future development of science and technology. It contains a large supply of strategic mineral deposits, including rare earths, copper, phosphorus, niobium, platinum-group elements, and other critical metals. The continued melting of the sea ice due to climate change makes these resources more accessible than ever before. However, the mineral exploration in the Arctic has always been a challenge due to the climatic restrictions, remote location, and vulnerability of Arctic ecosystems. This book covers a broad range of topics related to the problem of Arctic mineral resources, including geological, geochemical, and mineralogical aspects of their occurrence and formation; chemical technologies; and environmental and economic problems related to mineral exploration. The contributions can be tentatively classified into four major types: geodynamics and metallogeny, mineralogy and petrology, mineralogy and crystallography, and mining and chemical technologies associated with the exploration of mineral deposits and the use of raw materials for manufacturing new products. The book can be of interest for all those interested in Arctic issues and especially in Arctic mineral resources and associated problems of mineralogy, geology, geochemistry, and technology.

Keywords

forsterite --- typochemistry --- crystal structure --- Kovdor phoscorite–carbonatite complex --- pyrochlore supergroup minerals --- typochemistry --- crystal structure --- Kovdor phoscorite-carbonatite complex --- pyrrhotite --- chalcopyrite --- pentlandite --- cobaltpentlandite --- typochemistry --- crystal structure --- Kovdor phoscorite-carbonatite complex --- shkatulkalite --- titanosilicate --- crystal structure --- Kola Peninsula --- Lovozero alkaline massif --- transformation mineral species --- vuonnemite --- titanium --- niobium --- heap leaching --- bacterial leaching --- cryomineralogenesis --- low-grade copper-nickel ore --- raw materials --- apatite-nepheline-titanite ore --- sulfuric-acidic decomposition --- titanyl sulfate --- hydrothermal synthesis --- ivanyukite --- batievaite-(Y) --- hainite-(Y) --- titanosilicate --- rinkite group minerals --- Kola Peninsula --- Sakharjok massif --- Keivy alkaline province --- transformation mineral species --- vanadium mineralization --- mineralogy --- Paleoproterozoic --- Kola region --- Arctic zone --- Fennoscandian Shield --- zircon --- macrocrysts --- kimberlite --- trace elements --- geochronology --- cathodoluminescence --- Ti-in-zircon geothermometry --- antigorite --- ore dressing tailings --- mechanical activation --- alkali-activated binder --- Yenisei-Khatanga basin --- Siberian craton --- Arctic --- oil --- gas --- petroleum potential --- geodynamics --- apatite --- Khibiny --- apatite-nepheline deposit --- phase diagram apatite-nepheline-diopside --- silicocarbonatite --- melteigite --- calcite --- nepheline --- zeolite group minerals --- garnet --- crystal fractionation --- Breivikbotn --- Northern Norway --- saponite-containing waters --- diamond processing plants --- cryogenic treatment --- electrochemical separation --- saponite product applications --- U mineralization --- hydrothermal deposits --- U-Pb --- Rb-Sr --- Kola region --- evolution of the composition --- basic rocks --- Precambrian --- search of trend differences --- geodynamic evolution --- metallogeny --- beryllium minerals --- chemical composition --- mineral data --- alkaline rocks --- granite --- pegmatites --- hydrothermal veins --- Kola Peninsula --- Plume --- LIP --- PGE --- Palaeoproterozoic --- mafic intrusion --- U-Pb --- isotopes --- PGE --- South Reef --- West-Pana intrusion --- Fedorova-Pana Complex --- zircon dating --- U-Pb --- Khibiny promising structures --- conductive layers --- MHD-source “Khibiny”, Pechenga structure --- Kola Peninsula --- greenstone belt --- gold --- Kola Peninsula --- Northern Karelia --- rock alteration --- n/a

Flow and Transport Properties of Unconventional Reservoirs 2018

Authors: --- --- ---
ISBN: 9783039211166 / 9783039211173 Year: Pages: 364 DOI: 10.3390/books978-3-03921-117-3 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2019-08-28 11:21:27
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Unconventional reservoirs are usually complex and highly heterogeneous, such as shale, coal, and tight sandstone reservoirs. The strong physical and chemical interactions between fluids and pore surfaces lead to the inapplicability of conventional approaches for characterizing fluid flow in these low-porosity and ultralow-permeability reservoir systems. Therefore, new theories and techniques are urgently needed to characterize petrophysical properties, fluid transport, and their relationships at multiple scales for improving production efficiency from unconventional reservoirs. This book presents fundamental innovations gathered from 21 recent works on novel applications of new techniques and theories in unconventional reservoirs, covering the fields of petrophysical characterization, hydraulic fracturing, fluid transport physics, enhanced oil recovery, and geothermal energy. Clearly, the research covered in this book is helpful to understand and master the latest techniques and theories for unconventional reservoirs, which have important practical significance for the economic and effective development of unconventional oil and gas resources.

Keywords

fracturing fluid --- rheology --- chelating agent --- viscosity --- polymer --- fluid-solid interaction --- velocity profile --- the average flow velocity --- flow resistance --- pore network model --- shale gas --- volume fracturing --- finite volume method --- production simulation --- multi-scale flow --- multi-scale fracture --- shale gas reservoir --- fractured well transient productivity --- succession pseudo-steady state (SPSS) method --- complex fracture network --- multi-scale flow --- analysis of influencing factors --- tight sandstones --- spontaneous imbibition --- remaining oil distributions --- imbibition front --- imbibition recovery --- NMR --- slip length --- large density ratio --- contact angle --- pseudo-potential model --- lattice Boltzmann method --- micro-fracture --- dissolved gas --- experimental evaluation --- reservoir depletion --- recovery factor --- tight oil --- Lucaogou Formation --- tight oil --- pore structure --- prediction by NMR logs --- tight oil reservoir --- SRV-fractured horizontal well --- multiporosity and multiscale --- flow regimes --- productivity contribution degree of multimedium --- equilibrium permeability --- non-equilibrium permeability --- matrix–fracture interaction --- effective stress --- coal deformation --- porous media --- non-linear flow --- conformable derivative --- fractal --- hydraulic fracturing --- tight reservoirs --- fracture diversion --- extended finite element method --- fracture network --- gas adsorption capacity --- shale reservoirs --- influential factors --- integrated methods --- sulfonate gemini surfactant --- thickener --- temperature-resistance --- clean fracturing fluid --- low-salinity water flooding --- clay mineral composition --- enhanced oil recovery --- wetting angle --- pH of formation water --- fractional diffusion --- fractal geometry --- analytical model --- shale gas reservoir --- carbonate reservoir --- petrophysical characterization --- pore types --- pore structure --- permeability --- fractal dimension --- reservoir classifications --- deep circulation groundwater --- groundwater flow --- geothermal water --- faults --- isotopes --- shale permeability --- local effect --- global effect --- matrix-fracture interactions --- nanopore --- pore structure --- shale --- tight sandstone --- mudstone --- nitrogen adsorption --- fractal --- enhanced geothermal system --- well-placement optimization --- fracture continuum method --- 0-1 programming --- unconventional reservoirs --- petrophysical characterization --- fluid transport physics

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