Search results: Found 8

Listing 1 - 8 of 8
Sort by
Catalytic soot oxidation by platinum on sintered metal filters. Influence of the platinum quantity, particle size and location, and investigation of the platinum-soot contact

Author:
ISBN: 9783866441033 Year: Pages: VII, 135 p. DOI: 10.5445/KSP/1000005906 Language: ENGLISH
Publisher: KIT Scientific Publishing
Subject: Chemical Engineering
Added to DOAB on : 2019-07-30 20:02:00
License:

Loading...
Export citation

Choose an application

Abstract

The great challenge for next years concerning the emission of diesel engines is to develop diesel particle filters (DPF) with catalytic regeneration systems. This work is focused on the global understanding of the diesel soot oxidation on sintered metal filters (SMF). Platinum is studied as reference catalyst. The first objective is to determine which of platinum quantity, platinum particle size, or platinum location exhibits the preponderant influence on the catalytic.

A Commemorative Issue in Honor of Professor Nick Hadjiliadis: Metal Complex Interactions with Nucleic Acids and/or DNA

Authors: ---
ISBN: 9783038975113 / 9783038975120 Year: Pages: 256 DOI: 10.3390/books978-3-03897-512-0 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Biochemistry --- Biology --- Medicine (General) --- Therapeutics
Added to DOAB on : 2019-02-05 12:36:28
License:

Loading...
Export citation

Choose an application

Abstract

This Special Issue of the International Journal of Molecular Science comprises a comprehensive study on “Metal Complex Interactions with Nucleic Acids and/or DNA”. This Special Issue has been inspired by the important contribution of Prof. Nick Hadjiliadis to the field of palladium or/and platinum/nucleic acid interactions. It covers a selection of recent research and review articles in the field of metal complex interactions with nucleic acids and/or DNA. Moreover, this Special Issue on "Metal Complexes Interactions with Nucleic Acids and/or DNA" provides an overview of this increasingly diverse field, presenting recent developments and the latest research with particular emphasis on metal-based drugs and metal ion toxicity.

New Results and Advances in PGE Mineralogy in Ni-Cu-Cr-PGE Ore Systems

Authors: ---
ISBN: 9783039217168 / 9783039217175 Year: Pages: 228 DOI: 10.3390/books978-3-03921-717-5 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General)
Added to DOAB on : 2019-12-09 16:39:37
License:

Loading...
Export citation

Choose an application

Abstract

The book (Special Issue) presents impressive new results related to a wide spectrum of occurrences of platinum-group minerals (PGM) and natural compounds enriched in platinum-group elements (PGE), which are associated with various complexes and deposits, such as Uralian-Alaskan-type complexes, layered intrusions and placers. The geographical locations of the involved deposits and complexes include, on a truly international scale, different areas of the Urals, Western and Eastern Sayans and Gornaya Shoria in Siberia, Southern Central Asian Orogenic Belt in China, Northern Michigan, USA, South Africa and Zimbabwe, etc. Of particular interest is the first description of a new species of PGM, thalhammerite (approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association), which is a new species of palladium-silver sulfobismuthide discovered in the Noril’sk region of Russia. Additionally, comprehensive reviews, on compositional variations in Pt–Fe alloy minerals and processes of transformations of PGM in exogenic environments, are presented which will also attract attention from international readers.

Keywords

platinum-group elements --- platinum-group minerals --- PGE alloys --- chromian spinel --- schemes of substitution --- Ti- and REE-rich inclusions --- Sisim placer zone --- Lysanskiy complex --- Eastern Sayans --- Russia --- platinum-group elements --- gold --- platinum-group minerals --- placer deposits --- ophiolite complexes --- western Sayans --- Russia --- thalhammerite --- platinum-group mineral --- Pd9Ag2Bi2S4 phase --- reflectance data --- X-ray-diffraction data --- crystal structure --- Komsomolsky mine --- Talnakh deposit --- Noril’sk region --- Russia --- chromitite --- platinum group minerals --- primary inclusions --- ophiolite --- Alaskan-type complex. --- Urals --- Russia --- Alaskan-type complex --- Central Asian Orogenic Belt --- PGM --- PGE mineralization --- Bushveld Complex --- South Africa --- Great Dyke --- Zimbabwe --- platinum-group minerals --- primary ores --- oxide ores --- placers --- allogenic --- authigenic --- Echo Lake --- Midcontinent --- palladium --- platinum --- magnetite --- gabbro --- platinum-group elements --- platinum-group minerals --- Pt–Fe alloys --- compositional variations --- element substitutions --- placer deposits --- ore mineralization --- ultramafic-mafic complexes --- Ural Platinum belt --- Ural-Alaskan massif --- Svetloborsky massif --- placer system --- platinum group elements --- platinum group minerals --- platiniferous tetra-auricupride --- Pt-for-Au substitution --- platinum --- gold --- ophiolite --- Bolshoy Khailyk placer --- western Sayans --- Russia --- platinum-group elements --- gold --- platinum-group minerals --- placer deposits --- micrometric inclusions --- Gornaya Shoria --- Siberia --- Russia --- n/a

Geomicrobiology and Biogeochemistry of Precious Metals

Authors: ---
ISBN: 9783038973461 9783038973478 Year: Pages: 182 DOI: 10.3390/books978-3-03897-347-8 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Biotechnology --- Ecology --- Geology --- Earth Sciences --- Environmental Sciences
Added to DOAB on : 2018-11-20 10:57:53
License:

Loading...
Export citation

Choose an application

Abstract

Precious metals continue to have economic and sociocultural importance, as their usage evolves and diversifies over time. Today, the industrial application of precious metals is increasing with the development of scientific and technological innovations. Especially, the biological cycling of these metals is receiving more and more attention, as the microbiota may be key to a range of issues regarding exploration, ore-processing and metallurgy, and the processing of electron waste. In this volume, we focus on enhancing the fundamental understanding of the biological processes that drive noble metal cycling and examine how this knowledge may be turned into biotechnolical applications.

Unconventional Anticancer Metallodrugs and Strategies to Improve their Pharmacological Profile

Author:
ISBN: 9783039213153 / 9783039213160 Year: Pages: 204 DOI: 10.3390/books978-3-03921-316-0 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Biology --- Biochemistry
Added to DOAB on : 2019-12-09 11:49:15
License:

Loading...
Export citation

Choose an application

Abstract

For the past 40 years, metal-based drugs have been widely used for the treatment of cancer. Cisplatin and follow-up drugs carboplatin (ParaplatinTM) and oxaliplatin (EloxatinTM) have been the gold standard for metallodrugs in clinical settings as antineoplastic agents. While effective, these drugs (either alone or in combination therapy) have faced a number of clinical challenges resulting from their limited spectrum of activity, high toxicity leading to significant side effects, resistance, poor water solubility, low bioavailability and short circulating time. In the past 10 years, various unconventional non-platinum metal-based agents have emerged as a potential alternative for cancer treatment. These compounds are highly effective and selective in cancers resistant to cisplatin and other chemotherapeutic agents. Research in this area has recently exploded with a relevant number of patents and clinical trials, in addition to reports in scientific journals. Furthermore, in parallel to the synthesis of coordination and organometallic compounds comprising many different metals and unconventional platinum-based derivatives, researchers are focused on optimizing mechanistic and pharmacological features of promising drug candidates. This Special Issue aims to highlight the latest advances in anticancer metallodrugs with a focus on unconventional anticancer agents, as well as novel activation, targeting and delivery strategies aimed at improving their pharmacological profile.

Electrochemical Surface Science: Basics and Applications

Authors: ---
ISBN: 9783039216420 / 9783039216437 Year: Pages: 398 DOI: 10.3390/books978-3-03921-643-7 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General) --- Inorganic Chemistry
Added to DOAB on : 2019-12-09 11:49:15
License:

Loading...
Export citation

Choose an application

Abstract

Electrochemical surface science (EC-SS) is the natural advancement of traditional surface science (where gas–vacuum/solid interfaces are studied) to liquid (solution)/electrified solid interfaces. Such a merging between two different disciplines—i.e., surface science (SS) and electrochemistry—officially advanced ca. three decades ago. The main characteristic of EC-SS versus electrochemistry is the reductionist approach undertaken, inherited from SS and aiming to understand the microscopic processes occurring at electrodes on the atomic level. A few of the exemplary keystone tools of EC-SS include EC-scanning probe microscopies, operando and in situ spectroscopies and electron microscopies, and differential EC mass spectrometry (DEMS). EC-SS indirectly (and often unconsciously) receives a great boost from the requirement for rational design of energy conversion and storage devices for the next generation of energetic landscapes. As a matter of fact, the number of material science groups deeply involved in such a challenging field has tremendously expanded and, within such a panorama, EC and SS investigations are intimately combined in a huge number of papers. The aim of this Special Issue is to offer an open access forum where researchers in the field of electrochemistry, surface science, and materials science could outline the great advances that can be reached by exploiting EC-SS approaches. Papers addressing both the basic science and more applied issues in the field of EC-SS and energy conversion and storage materials have been published in this Special Issue.

Keywords

electrosynthesis --- switchable surfaces --- alkoxyamine surfaces --- redox monolayers --- porphyrins --- self-assembly --- surface nanostructures --- in situ EC-STM --- metal-electrolyte interface --- potential-dependent structures --- combined non-covalent control --- ECALE --- CdS --- silver single crystals --- alkanthiols --- SAMs --- EQCM --- AES --- polypyrrole --- diazonium salts --- flexible ITO --- adhesion --- redox properties --- X-ray absorption spectroscopy --- energy dispersive --- quick-XAS --- FEXRAV --- free electron laser --- electrochemistry --- photoelectrochemistry --- photochemistry --- pump &amp --- probe --- oxygen evolution reaction --- water splitting --- iridium --- thin-films --- spin-coating --- model systems --- electrocatalysts --- oxygen evolution reaction --- iridium --- nickel --- electrodeposition --- model catalyst --- water oxidation --- CO oxidation --- DFT --- hydrogen adsorption --- Pt–Ru catalysts --- ordered mesoporous carbons --- graphitization --- CO oxidation --- methanol oxidation --- direct methanol fuel cells --- electrocatalysis --- catalysts --- methanol oxidation reaction --- graphene --- DMFC --- Pt --- SOFC --- cathode --- XAFS --- in situ --- cobalt oxide --- water oxidation --- photo-electrochemistry --- hydroxyl radical --- electro-oxidation --- Lead OPD --- surface alloy --- XPS --- UPS --- EF-PEEM --- ORR --- Platinum --- PVDF --- PEMFC --- in situ ambient pressure XPS --- hard X rays --- photoelectron simulations --- solid/liquid interface --- TiO2 --- APTES --- Cu(111) --- electrochemical interface --- in-situ X-ray diffraction --- carbon nanofiber --- porous fiber --- electrospinning --- mesopore --- micropore --- porogen --- ammonia activation --- surface area --- methanol oxidation --- platinum single crystals --- pH and concentration effects --- adsorbed OH --- reduced graphene oxide --- electrophoretic deposition --- surface chemistry --- click chemistry --- gold --- palladium --- bimetallic alloy --- carbon nanofibers (CNFs) --- cyclic voltammetry (CV) --- Surface Modification --- Blackening of Steel --- Magnetite --- Corrosion Protection --- Auger-Electron Spectroscopy --- Ordered mesoporous carbon --- nitrogen doping --- cobalt-based electrocatalyst --- bifunctional oxygen electrode --- solvothermal method --- underpotential deposition (upd) --- Au --- Pt --- Pd --- nanoparticles --- cyclic voltammetry --- electrocatalysis --- operando --- near ambient pressure XPS --- scanning photoelectron microscopy --- solid oxide fuel cells --- surface science --- electrodeposited alloys --- CO electro-oxidation --- Pt single-crystal electrodes --- potential cycling --- potential stepping --- surface reconstruction --- electrocatalysis --- oxygen reduction --- ORR --- gas diffusion electrode --- platinum --- fuel cells --- thin-films --- benchmarking --- mass transport --- formic acid oxidation --- Au nanocrystals --- Pd thin films --- electrocatalysis --- d-band theory --- polymer --- silicon nanoparticles --- EPR spectroscopy --- photoconversion --- n/a

Coordination Chemistry of Silicon

Author:
ISBN: 9783038976387 Year: Pages: 225 DOI: 10.3390/books978-3-03897-639-4 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General) --- Inorganic Chemistry
Added to DOAB on : 2019-03-08 11:42:05
License:

Loading...
Export citation

Choose an application

Abstract

The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.

Keywords

silanetriols --- disiloxane tetrols --- silsesquioxanes --- condensation --- molecular cage --- platinum --- primary silane --- hydrido complex --- oxidative addition --- ligand-exchange reaction --- X-ray crystallography --- Si–Cl activation --- germylene --- digermene --- digermacyclobutadiene --- palladium --- cluster --- cyclic organopolysilane --- template --- bridging silylene ligand --- isocyanide --- hydrogen bonds --- silicon --- 2-silylpyrrolidines --- stereochemistry --- X-ray crystallography --- Baird’s rule --- computational chemistry --- excited state aromaticity --- Photostability --- dye-sensitized solar cell --- disilanylene polymer --- photoreaction --- surface modification --- TiO2 --- silylene --- germylene --- N-heterocyclic carbene --- oxidative addition --- siloxanes --- host-guest chemistry --- supramolecular chemistry --- main group coordination chemistry --- hydrogen bonding --- adsorption --- bond activation --- bonding analysis --- density functional theory --- distorted coordination --- molecular orbital analysis --- silicon surfaces --- disilene --- functionalization --- ?-electron systems --- silicon --- N-heterocyclic carbenes --- bromosilylenes --- silyliumylidenes --- dehydrobromination --- silicon cluster --- siliconoid --- nanoparticle --- computation --- silicon --- N-heterocyclic carbenes --- silyliumylidenes --- small molecule activation --- mechanistic insights --- organosilicon --- reductant --- N-Heterocyclic tetrylene --- salt-free --- germanium --- germanethione --- germathioacid chloride --- N-heterocyclic carbines --- ?-chloro-?-hydrooligosilane --- titanium --- ruthenium --- dehydrogenative alkoxylation --- cluster --- isomerization --- silicon --- siliconoid --- subvalent compounds --- AIM --- DFT --- intermetallic bond --- 29Si NMR spectroscopy --- X-ray diffraction

Carbon Based Electronic Devices

Authors: ---
ISBN: 9783039282326 / 9783039282333 Year: Pages: 258 DOI: 10.3390/books978-3-03928-233-3 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: General and Civil Engineering --- Technology (General)
Added to DOAB on : 2020-04-07 23:07:08
License:

Loading...
Export citation

Choose an application

Abstract

For more than 50 years, silicon has dominated the electronics industry. However, this growth will come to an end, due to resources limitations. Thus, research developments need to focus to alternative materials, with higher performance and better functionality. Current research achievements have indicated that carbon is one of the promising candidates for its exploitation in the electronics industry. Whereas the physical properties of graphite and diamond have been investigated for many years, the potential for electronic applications of other allotropes of carbon (fullerenes, carbon nanotubes, carbon nanofibres, carbon films, carbon balls and beads, carbon fibers, etc), has only been appreciated relatively recently. Carbon-based materials offer a number of exciting possibilities for new applications of electronic devices, due to their unique thermal and electrical properties. However, the success of carbon-based electronics depends on the rapid progress of the fabrication, doping and manipulation techniques. In this Special Issue, we focus on both insights and advancements in carbon-based electronics. We will also cover various topics ranging from synthesis, functionalisation, and characterisation of carbon-based materials, for their use in electronic devices, including advanced manufacturing techniques, such as 3D printing, ink-jet printing, spray-gun technique, etc.

Keywords

ionization sensor array --- NOx --- carbon nanotube (CNT) --- selectivity --- non-self-sustaining discharge --- carbon nanotube --- field emitters --- electrical aging --- Joule heating --- electron emission --- photosensor --- reduced graphene oxide --- Ag nanoparticles --- solution process --- finite-difference time-domain --- carbon nanofibres (CNFs) --- active-screen plasma sputtering (ASPS) technology --- supercapacitors (SCs) --- silver (Ag) --- platinum (Pt) and palladium (Pd) nanoparticles --- transparent conducting electrode --- flexible electrode --- graphene --- optoelectronic device --- graphene --- Galinstan --- Liquid-Metal --- spray-on --- aerosol --- honey --- mobility --- contact resistance --- TLM --- I-V characteristics --- porous electrode --- pressure sensitivity --- self-powered sensors --- mechanical impact --- carbon nanofillers --- electrical conductivity --- piezoresistive behavior --- ReRAM --- carbon nanofibers --- spray-gun deposition --- carbon Inks --- rheology --- additive manufacturing --- graphene --- carbon nanotubes --- printing --- supercapacitors --- graphene oxide --- metal nanoparticles --- dodecylbenzene sulfonic acid (DBSA) doped polyaniline --- capacitance --- humidity sensor --- carbon-based materials --- carbon nanotubes --- graphene --- carbon black --- carbon fibers --- carbon soot --- biochar --- flexible electronics --- carbon nanotubes --- graphene --- carbon fibres --- functionalization --- supercapacitors --- sensors --- inkjet printer inks --- flexible wearable devices --- electronics --- carbon-based material --- carbon structure differentiation --- NEMS quality --- higher performances --- revised Raman characterization --- quantum electronic activation --- carbon phase transition --- n/a

Listing 1 - 8 of 8
Sort by
Narrow your search
-->