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Polymer Clay Nano-composites

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ISBN: 9783039216529 / 9783039216536 Year: Pages: 246 DOI: 10.3390/books978-3-03921-653-6 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Biology
Added to DOAB on : 2019-12-09 11:49:16
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Abstract

This Special Issue focuses on the current state-of-the-art of “Polymer Clay Nano-Composites” for biomedical, anticorrosion, antibacterial, and other applications. Clay–polymer composite nanomaterials represent an emerging area of research. Loading polymers with clay particles essentially enhances the composite strength features. Of particular interest are different nano-assembly methods, such as silane mono and multilayers, polyelectrolyte layer-by-layer assembly, and others. An important development was reached for tubular and fibrous clay nanoparticles, such as halloysite, sepiolite, and imogolite. Polymer clay nanoparticles can be prepared as sheets with 1-nm thickness and width of a few hundred nm (e.g., kaolin and montmorillonite). Fibrous clays significantly reinforce the nano-composites in the assembly with biopolymers and other green polymers, leading to functional hybrid bio nano-composites. The scope of this Special Issue comprehensively includes the synthesis and characterization of polymer clay nano-composites used for several applications, including nano-clay polymer composites and hybrid nano-assemblies.

Keywords

polyimide --- graphene oxide --- composite --- mechanical properties --- indentation recovery --- AFM --- carbon fibers --- surface grafting --- halloysite nanotubes --- polymer composites --- interface --- fish gelatin --- halloysite nanotubes --- glycerol --- mechanical properties --- water resistance --- LAP --- hyaluronic acid --- doxorubicin --- CD44 receptor targeted --- sacrificial bond --- ionic network --- organic montmorillonite --- 1,2-polybutadiene --- in-situ intercalation --- clay–polymer nanocomposites --- atrazine --- radical polymerization --- hexadecyltrimethylammonium bromide --- phenyltrimethylammonium chloride --- FTIR --- TGA --- adsorption --- dental resins --- nanocomposite materials --- organically modified clays --- montmorillonite --- intercalation --- nanotechnology --- ammonium persulfate --- fuzzy optimization --- N,N?-methylenebisacrylamide --- Pareto set --- polyacrylic acid --- swelling capacity --- variable cost --- polyethylene oxide --- montmorillonite clays --- Pd catalysis --- catalytic composite --- positron annihilation --- doubly functionalized montmorillonite --- polystyrene --- soap-free emulsion polymerization --- thermal stability --- tribological property --- organo-clays --- polyamines --- clay-amine interaction mechanisms --- structure effects --- la uptake and release --- layered silicate --- sericite --- CTAB --- intercalation stability --- nanocomposites --- gelation kinetics --- sol–gel transition --- water shutoff --- silica sol --- cellulose nanofibrils --- halloysite nanotubes --- supercritical CO2 --- polystyrene foam --- blowing agent --- in situ polymerization --- attapulgite/polypyrrole nanocomposite --- halloysite nanotubes --- polysaccharide --- interfacial interactions --- reinforcing --- adsorption --- dispersion --- coatings --- whey protein isolate --- nanocomposites --- nanoclay, barrier --- morphology --- n/a

Advances in Experimental and Computational Rheology

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ISBN: 9783039213337 / 9783039213344 Year: Pages: 224 DOI: 10.3390/books978-3-03921-334-4 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General)
Added to DOAB on : 2019-12-09 16:10:12
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Rheology, defined as the science of deformation and flow of matter, is a multidisciplinary scientific field, covering both fundamental and applied approaches. The study of rheology includes both experimental and computational methods, which are not mutually exclusive. Its practical importance embraces many processes, from daily life, like preparing mayonnaise or spread an ointment or shampooing, to industrial processes like polymer processing and oil extraction, among several others. Practical applications include also formulations and product development. This Special Issue aims to present the latest advances in the fields of experimental and computational rheology applied to the most diverse classes of materials (foods, cosmetics, pharmaceuticals, polymers and biopolymers, multiphasic systems and composites) and processes. This Special Issue will comprise, not only original research papers, but also review articles.

Polymeric Foams

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ISBN: 9783039216321 / 9783039216338 Year: Pages: 322 DOI: 10.3390/books978-3-03921-633-8 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- Chemical Engineering
Added to DOAB on : 2019-12-09 11:49:16
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Advances in nanotechnology have boosted the development of more efficient materials, with emerging sectors (electronics, energy, aerospace, etc.) demanding novel materials to fulfill the complex technical requirements of their products. This is the case of polymeric foams, which may display good structural properties alongside functional characteristics through a complex composition and (micro)structure in which a gas phase is combined with rigid ones, mainly based on nanoparticles, dispersed throughout the polymer matrix. In recent years, there has been an important impulse in the development of nanocomposite foams, extending the concept of nanocomposites to the field of cellular materials. This, alongside developments in new advanced foaming technologies which have allowed the generation of foams with micro, sub-micro, and even nanocellular structures, has extended the applications of more traditional foams in terms of weight reduction, damping, and thermal and/or acoustic insulation to novel possibilities, such as electromagnetic interference (EMI) shielding. This Special Issue, which consists of a total of 22 articles, including one review article written by research groups of experts in the field, considers recent research on novel polymer-based foams in all their aspects: design, composition, processing and fabrication, microstructure, characterization and analysis, applications and service behavior, recycling and reuse, etc.

Keywords

grey relational analysis --- multi-objective particle swarm optimization --- acoustic performances --- Ethylene Propylene Diene Monomer --- polyurethane foam composites --- DOPO --- itaconic acid --- ethyl cellulose --- phenolic foams --- composites --- adjacent façade --- PUR --- energy conservation --- heat transfer --- burning characteristic --- semi-rigid polyurethane foams --- aluminum microfibers --- quasi-static compression tests --- mechanical properties --- energy absorption capability --- foams --- polyamide --- crystalline --- thermal conductivity --- mechanical property --- functional --- biomaterials --- composites --- EMI --- cellulose foam --- polypropylene --- foaming quality --- impact property --- intrinsic toughness --- flame-retardant ABS microcellular foams --- phosphorus flame retardants --- MuCell® injection-molding foaming --- graphene oxide --- rigid polyurethane foam --- thermogravimetric analysis --- activation energies --- extrusion foaming --- super critical CO2 --- lignin --- sound absorption coefficient --- mechanical property --- Pluronic --- surfactants --- foams --- SANS --- multilayers --- epoxy composite foam adhesive --- core–shell rubber --- impact wedge–peel test --- automobile structural adhesives --- flame retardancy --- foams --- phosphorus --- ternary synergistic effect --- polypropylene --- fluoelastomer --- scCO2 foaming --- heterogeneous nucleation --- polypropylene --- cellulose nanofiber --- foam injection molding --- mechanical properties --- polystyrene foams --- 1,3,5-benzene-trisamides --- cell nucleation --- foam extrusion --- foam morphology --- supramolecular additives --- thermal insulation --- compression properties --- piezoelectric --- functional foam --- piezocomposite --- PZT --- expandable microspheres --- permittivity --- polyetherimide foams --- graphene --- multifunctional foams --- ultrasonication --- scCO2 --- electrical conductivity --- polymer waste --- polyurethane foam --- leaching test --- microstructure --- absorbent PMI foam --- metallic tube --- electromagnetic wave absorption --- mechanical properties --- failure mechanism --- polymers --- foams --- shock compression --- equation of state --- epoxy --- foams --- expandable microspheres --- graphene --- nanotubes --- conductivity --- syntactic foams --- n/a

Surface Modification to Improve Properties of Materials

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ISBN: 9783038977964 9783038977971 Year: Pages: 356 DOI: 10.3390/books978-3-03897-797-1 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2019-04-25 16:37:17
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This book contains selected contributions on surface modification to improve the properties of solid materials. The surface properties are tailored either by functionalization, etching, or deposition of a thin coating. Functionalization is achieved by a brief treatment with non-equilibrium gaseous plasma containing suitable radicals that interact chemically with the material surface and thus enable the formation of rather stable functional groups. Etching is performed in order to modify the surface morphology. The etching parameters are selected in such a way that a rich morphology of the surfaces is achieved spontaneously on the sub-micrometer scale, without using masks. The combination of adequate surface morphology and functionalization of materials leads to superior surface properties which are particularly beneficial for the desired response upon incubation with biological matter. Alternatively, the materials are coated with a suitable thin film that is useful in various applications from food to aerospace industries.

Keywords

sulphur hexafluoride (SF6) plasma --- tetrafluoromethane (CF4) plasma --- polymer polyethylene terephthalate (PET) --- surface modification --- functionalization and wettability --- optical emission spectroscopy (OES) --- electronegativity --- PVD nanocomposite coatings --- aluminum die casting --- tool life --- tribological performance --- plasma surface modification --- polymer polypropylene --- neutral oxygen atom density --- initial surface functionalization --- food packaging --- wettability --- tantalum --- hardness --- gradient nanostructured layer --- grain size --- residual stress --- dry wear behavior --- surface texture --- surface treatment --- Ti6Al4V alloy --- tribology --- biology --- materials characterization --- shot-peening --- image processing --- TIG welding --- aluminum 6061-T6 --- special surfaces --- wettability --- superhydrophobic --- cell cultures --- anti-bio adhesion --- self-cleaning fabrics --- polyethylene granules --- low-pressure MW air plasma --- optical emission spectroscopy --- XPS --- laser cobalt catalytic probe --- Alloy 718 --- surface hardness --- surface residual stress --- grain size --- fretting failure --- corrosion --- antimicrobial film --- nisin --- physical properties --- plasma treatment polyvinyl alcohol --- surface characterization --- microhole-textured tool --- CaF2 --- micro-EDM --- tribological properties --- egg shell --- stearic acid --- modification --- particle characterization --- epoxy composites --- dynamic mechanical analysis --- adhesion effectiveness --- Poly(tetrafluoroethylene) --- Teflon --- plasma treatment --- zeta potential --- surface energy --- contact angle measurement --- lectin --- bovine serum albumin --- adsorption --- cellulose thin film --- polystyrene --- gold --- surface plasmon resonance spectroscopy --- silver nanoparticles --- laser ablation in liquids --- laser synthesis of colloidal nanoparticles solution --- nanoparticle-impregnated paper --- antimicrobial activity --- fiber fines --- sheet forming --- vacuum filtration --- pulse power --- electrical stimulation --- electric field --- mushroom --- L. edodes --- Lyophyllum deeastes Sing --- surface modification --- porous silicon --- silicon surface --- carbonization --- oxidation --- aluminum --- alloy --- duralumin --- etching --- surface texture --- porous-like --- adhesive bonding --- superhydrophobic --- porous silicon --- visible light assisted organosilanization --- solid state NMR --- XPS --- ToF-SIMS --- atmospheric pressure plasma jets --- plasma polymerization --- superhydrophobicity --- wetting --- biomaterial --- polymer --- plasma --- functionalization --- surface properties --- thrombosis --- hemocompatibility --- endothealization --- vascular graft --- biocompatibility --- endothelial cells --- surface properties --- nanostructuring --- functionalization --- grafting

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MDPI - Multidisciplinary Digital Publishing Institute (4)


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eng (4)


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2019 (4)